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30417

Sigma-Aldrich

Phosphoric acid

puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥85%

Synonym(s):

Orthophosphoric acid

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1 L
$255.00
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$409.00

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1 L
$255.00
2.5 L
$409.00

About This Item

Linear Formula:
H3PO4
CAS Number:
Molecular Weight:
98.00
Beilstein/REAXYS Number:
1921286
EC Number:
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:

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grade

ACS reagent
puriss. p.a.

Quality Level

agency

USP/NF
reag. ISO
reag. Ph. Eur.

vapor density

3.4 (vs air)

vapor pressure

2.2 mmHg ( 20 °C)
5 mmHg ( 25 °C)

assay

≥85%

form

liquid

impurities

reducing impurities, in accordance
residual solvents, in accordance
substances precipitated by ammonia, in accordance
≤0.001% KMnO4 red. matter (as O)
≤0.001% heavy metals (as Pb)
≤0.001% in water insoluble matters
≤0.001% volatile acids (as CH3COOH)

bp

158 °C (lit.)

mp

~40 °C (lit.)

density

1.685 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤2 mg/kg
fluoride (F-): ≤1 mg/kg
nitrate (NO3-): ≤3 mg/kg
phosphite, hypophosphite (as H3PO3): ≤20 mg/kg
phosphite, hypophosphite (as H3PO3): in accordance
sulfate (SO42-): ≤30 mg/kg

cation traces

As: ≤0.5 mg/kg
Ca: ≤10 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤5 mg/kg
K: ≤5 mg/kg
Mg: ≤5 mg/kg
Mn: ≤0.5 mg/kg
Na: ≤20 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Sb: ≤2 mg/kg
Zn: ≤2 mg/kg

SMILES string

OP(O)(O)=O

suitability

passes test for appearance of solution

InChI

1S/H3O4P/c1-5(2,3)4/h(H3,1,2,3,4)

InChI key

NBIIXXVUZAFLBC-UHFFFAOYSA-N

Gene Information

human ... SRC(6714)

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1 of 4

This Item
0410769501779622
grade

ACS reagent, puriss. p.a.

grade

-

grade

ACS reagent

grade

-

assay

≥85%

assay

85.0-88.0%

assay

≥85% H3PO4 basis (by NaOH, titration)

assay

≥99.0% (T)

agency

USP/NF, reag. Ph. Eur., reag. ISO

agency

-

agency

-

agency

-

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

200

form

liquid

form

liquid

form

liquid

form

powder or crystals

impurities

reducing impurities, in accordance, substances precipitated by ammonia, in accordance, ≤0.001% heavy metals (as Pb), ≤0.001% volatile acids (as CH3COOH), residual solvents, in accordance, ≤0.001% in water insoluble matters, ≤0.001% KMnO4 red. matter (as O)

impurities

alkali phosphates, in accordance, residual solvents, in accordance, substance precip. by Ammonia, in accordance, ≤0.0005% heavy metals (as Pb), ≤0.001% volatile acids (as CH3COOH)

impurities

reducing substances, passes test, ≤0.001% volatile acids (as CH3COOH)

impurities

≤0.002% KMnO4-reducing matter (as O)

Application


  • Cooperative Rh/Achiral Phosphoric Acid-Enabled [3+3] Cycloannulation of Carbonyl Ylides with Quinone Monoimines: Synthesis of Benzofused Dioxabicyclo[3.2.1]octane Scaffolds.: This study demonstrates the catalytic role of phosphoric acid in a [3+3] cycloannulation reaction, enabling the efficient synthesis of complex organic scaffolds (Tu et al., 2024).

Other Notes

Concentrated phosphoric acid is approx. 85% H3PO4 (aqueous).
The article number 30417-4X2.5L will be discontinued. Please order the single bottle 30417-2.5L which is physically identical with the same exact specifications.
The article number 30417-4X2.5L-M will be discontinued. Please order the single bottle 30417-2.5L-M which is physically identical with the same exact specifications.
The article number 30417-6X1L will be discontinued. Please order the single bottle 30417-1L which is physically identical with the same exact specifications.
The article number 30417-6X1L-M will be discontinued. Please order the single bottle 30417-1L-M which is physically identical with the same exact specifications.

pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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