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306568

Potassium hydroxide

semiconductor grade, pellets, 99.99% trace metals basis (Purity excludes sodium content.)

Synonym(s):

Caustic potash

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Size/SKUAvailabilityPrice
100 g

Available to ship TODAYfromMILWAUKEE

$155.00
500 g

Available to ship TODAYfromMILWAUKEE

$514.00

About This Item

Linear Formula:
KOH
CAS Number:
Molecular Weight:
56.11
PubChem Substance ID:
eCl@ss:
38100303
UNSPSC Code:
12352106
NACRES:
NA.21
EC Number:
215-181-3
MDL number:
Assay:
99.99% trace metals basis (Purity excludes sodium content.)
Grade:
semiconductor grade
Form:
pellets
Solubility:
water: soluble

$155.00


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grade

semiconductor grade

Quality Segment

vapor pressure

1 mmHg ( 719 °C)

assay

99.99% trace metals basis (Purity excludes sodium content.)

form

pellets

composition

KOH, >85.0%

impurities

15% water

pH

~13.5 (25 °C, 5.6 g/L)

mp

361 °C (lit.)

solubility

water: soluble

cation traces

Na: ≤500.0 ppm

SMILES string

[OH-].[K+]

InChI

1S/K.H2O/h;1H2/q+1;/p-1

InChI key

KWYUFKZDYYNOTN-UHFFFAOYSA-M

General description

Potassium hydroxide (KOH), also known as caustic potash. It is used as a significant precursor to many potassium containing products.

Application

In combination with tellurium powder, mediates the quantitative pinacolization of aromatic carbonyl compounds.
Potassium hydroxide can be used:
  • As a base in the synthesis of imines, starting from amines and alcohols.
  • As a base in β-alkylation of secondary alcohols with primary alcohols without any transition metal catalyst.
  • In combination with aluminium for pinacolization of aromatic aldehydes and reduction of hindered ketones.
  • As a precipitating agent in the synthesis of MnZn ferrites nanoparticles (Mn0.8Zn0.2Fe2O4 ferrite nanoparticles) by modified hydrothermal method.


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This Item
7575510600506103
form

pellets

form

crystals or chunks, powder and chunks, powder or crystals

form

pellets

form

powder

solubility

water: soluble

solubility

H2O: soluble 1120 g/L

solubility

-

solubility

-

assay

99.99% trace metals basis (Purity excludes sodium content.)

assay

≥99.95% trace metals basis

assay

85-100.5%

assay

≥85%

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

200

grade

semiconductor grade

grade

anhydrous

grade

-

grade

-

pH

~13.5 (25 °C, 5.6 g/L)

pH

-

pH

~13.5 (25 °C, 5.6 g/L)

pH

~13.5 (25 °C, 5.6 g/L)


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pictograms

CorrosionExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable



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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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