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309966

Sigma-Aldrich

Diethyl ether

suitable for HPLC, ≥99.9%, inhibitor-free

Synonym(s):
Ethyl ether, Ether
Linear Formula:
(CH3CH2)2O
CAS Number:
Molecular Weight:
74.12
Beilstein:
1696894
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.07

Quality Level

vapor density

2.6 (vs air)

vapor pressure

28.69 psi ( 55 °C)
8.59 psi ( 20 °C)

assay

≥99.9%

form

liquid

autoignition temp.

320 °F

purified by

glass distillation

expl. lim.

36.5 %

application(s)

HPLC: suitable

impurities

≤0.03% water
≤1 ppm peroxides (as H2O2)

evapn. residue

<0.0003%

refractive index

n20/D 1.3530 (lit.)

bp

34.6 °C (lit.)

mp

−116 °C (lit.)

density

0.706 g/mL at 25 °C (lit.)

λ

H2O reference

UV absorption

λ: 218 nm Amax: 1.0
λ: 250 nm Amax: 0.20
λ: 275 nm Amax: 0.04
λ: 300-400 nm Amax: 0.01

Featured Industry

Food and Beverages

SMILES string

CCOCC

InChI

1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3

InChI key

RTZKZFJDLAIYFH-UHFFFAOYSA-N

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Related Categories

Packaging

100 mL in Sure/Seal™
1, 6×1 L in Sure/Seal™
20 L in Pure-Pac™ 2

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Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Flam. Liq. 1 - STOT SE 3

Target Organs

Central nervous system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK Germany

WGK 1

Flash Point(F)

-40.0 °F - closed cup

Flash Point(C)

-40 °C - closed cup

Certificate of Analysis

Certificate of Origin

Lana S Barkawi et al.
Nature protocols, 5(10), 1609-1618 (2010-10-05)
Auxin measurements in plants are critical to understanding both auxin signaling and metabolic homeostasis. The most abundant natural auxin is indole-3-acetic acid (IAA). This protocol is for the precise, high-throughput determination of free IAA in plant tissue by isotope dilution...
Diethyl ether (DEE) as a renewable diesel fuel.
Bailey B, et al.
No. 972978. SAE technical paper (1997)
Oxidation of secondary alcohols in diethyl ether with aqueous chromic acid. Convenient procedure for the preparation of ketones in high epimeric purity.
Brown HC, et al.
The Journal of Organic Chemistry, 36(3), 387-390 (1971)
Eagleson M.
Concise Encyclopedia Chemistry, 471-471 (1994)
Alessandra Forni et al.
Journal of molecular graphics & modelling, 38, 31-39 (2012-10-23)
The solvent effect on the I⋯O halogen bonding in complexes of iodobenzene derivatives with formaldehyde has been investigated by systematically varying the substituents on the iodobenzene ring. Calculations have been performed at MP2 and DFT levels of theory, using the...

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