31627

Carbon disulfide

suitable for IR spectroscopy, puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.9% (GC)

• Empirical Formula (Hill Notation): CS₂
• CAS Number: 75-15-0
• Molecular Weight: 76.14
• UNSPSC Code: 12352100
• NACRES: NA.21
• PubChem Substance ID: 329753851
• EC Number: 200-843-6
• Beilstein/REAXYS Number: 1098293
• MDL number: MFCD00011321
• Assay: ≥99.9% (GC)
• Technique(s): IR spectroscopy: suitable
• Bp: 46 °C (lit.)
• Vapor pressure: 5.83 psi

Properties

• Quality Level: 100
• agency: reag. Ph. Eur.
• vapor density: 2.67 (vs air)
• vapor pressure: 5.83 psi
• grade: ACS reagent, puriss. p.a.
• assay: ≥99.9% (GC)
• form: liquid
• autoignition temp.: 212 °F
• expl. lim.: 50 %
• technique(s): IR spectroscopy: suitable
• impurities: ≤0.0001% H₂S + foreign org. S-comp., ≤0.001% benzene, ≤0.001% non-volatile matter, ≤0.01% water (Karl Fischer)
• refractive index: n20/D 1.627 (lit.)
• bp: 46 °C (lit.)
• mp: −112-−111 °C (lit.)
• density: 1.266 g/mL at 25 °C (lit.)
• anion traces: sulfate (SO₄^2-): ≤2.5 mg/kg, sulfite (SO₃^2-): ≤10 mg/kg
• SMILES string: S=C=S
• InChI: 1S/CS2/c2-1-3
• InChI key: QGJOPFRUJISHPQ-UHFFFAOYSA-N

Description

General description

Carbon disulfide is a sulfur containing gas. Its natural and anthropogenic sources of emissions in earth atmosphere has been investigated. Its lifetime in atmosphere has been proposed to be around 12 days. It is a non-polar solvent.

Application

Carbon disulfide may be used in the preparation of dibenzyl trithiocarbonate, a RAFT (reversible addition-fragmentation transfer) chain-transfer agent (CTA).[1] It may be employed as solvent in the preparation of benzyl chlorodithioformate.

Safety Information

• pictograms: GHS02,GHS08,GHS07
• signalword: Danger
• hcodes: H225,H315,H319,H332,H361fd,H372
• pcodes: P202 - P210 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1
• target_organs: Peripheral nervous system,Central nervous system,Cardio-vascular system,Eyes
• Storage Class: 3 - Flammable liquids
• wgk: WGK 2
• flash_point_f: -22.0 °F - closed cup
• flash_point_c: -30 °C - closed cup