32213

Methanol

≥99.8% (GC), ACS reagent, reag. Ph. Eur., reag. ISO, USP/NF

• Synonym(s): Methyl alcohol
• Linear Formula: CH₃OH
• CAS Number: 67-56-1
• Molecular Weight: 32.04
• NACRES: NA.05
• PubChem Substance ID: 329754104
• UNSPSC Code: 12352104
• EC Number: 200-659-6
• MDL number: MFCD00004595
• Beilstein/REAXYS Number: 1098229
• Assay: ≥99.8% (GC)
• Technique(s): immunofluorescence: suitable
• Bp: 64.7 °C (lit.)
• Vapor pressure: 410 mmHg ( 50 °C), 97.68 mmHg ( 20 °C)

Properties

• Product Name: Methanol, puriss. p.a., ACS reagent, reag. ISO, reag. Ph. Eur., ≥99.8% (GC)
• Quality Segment: 200
• agency: USP/NF, reag. ISO, reag. Ph. Eur.
• vapor density: 1.11 (vs air)
• vapor pressure: 410 mmHg ( 50 °C), 97.68 mmHg ( 20 °C)
• grade: ACS reagent, puriss. p.a.
• assay: ≥99.8% (GC)
• form: liquid
• autoignition temp.: 725 °F
• expl. lim.: 36 %
• technique(s): immunofluorescence: suitable
• impurities: ≤0.00005% free alkali (as NH₃), ≤0.0001% formaldehyde, ≤0.00025% KMnO₄ red. matter (as O), ≤0.0005% non-volatile matter, ≤0.001% acetaldehyde, ≤0.001% acetone (GC), ≤0.05% water (Karl Fischer), ≤0.1% ethanol (GC)
• refractive index: n20/D 1.329 (lit.)
• bp: 64.7 °C (lit.)
• mp: −98 °C (lit.)
• density: 0.791 g/mL at 25 °C (lit.)
• anion traces: chloride (Cl^-): ≤0.5 mg/kg, sulfate (SO₄^2-): ≤1 mg/kg
• SMILES string: CO
• cation traces: Al: ≤0.5 mg/kg, B: ≤0.02 mg/kg, Ba: ≤0.1 mg/kg, Bi: ≤0.1 mg/kg, Ca: ≤0.5 mg/kg, Cd: ≤0.05 mg/kg, Co: ≤0.02 mg/kg, Cr: ≤0.02 mg/kg, Cu: ≤0.01 mg/kg, Fe: ≤0.1 mg/kg, K: ≤0.5 mg/kg, Li: ≤0.1 mg/kg, Mg: ≤0.1 mg/kg, Mn: ≤0.01 mg/kg, Mo: ≤0.1 mg/kg, Na: ≤0.5 mg/kg, Ni: ≤0.02 mg/kg, Pb: ≤0.02 mg/kg, Sn: ≤0.1 mg/kg, Sr: ≤0.1 mg/kg, Zn: ≤0.1 mg/kg
• format: neat
• InChI: 1S/CH4O/c1-2/h2H,1H3
• InChI key: OKKJLVBELUTLKV-UHFFFAOYSA-N

Description

General description

Methanol is an organic solvent that can be synthesized from syngas in the presence of CuO/ZnO/Al₂O₃ catalysts. It is an ideal candidate as a hydrogen source in fuel cell technology due to its high H/C ratio, low propensity for soot generation, relatively low reforming temperature and as it exists in liquid state at room temperature. In a direct methanol fuel cell (DMFC), methanol undergoes oxidation with air to generate electricity. The olefins (ethylene or propylene) formed from methanol via MTO (methanol-to-olefins) process, can be an alternate to oil and gas to produce hydrocarbon fuels.

Thermochemical conversion of methanol to C₂-C₁₀ hydrocarbons in the presence of shape-selective zeolites has been reported. Its oxidation on Ru-Pt catalyst system by ruthenium ad-atoms has been proposed.

Application

Methanol was used in the following studies:

• Colony forming unit-fibroblast assay of bone marrow mononuclear cells.
• As solvent for the preparation of extracts of hyphae of Aspergillus for the estimation of gliotoxin by reversed phase-HPLC.
• Immunofluorescence studies.

Packaging

In PE-bottles; also available Glass-bottles (Material no. ending with *-GL)

Other Notes

The article number 32213-4X2.5L will be discontinued. Please order the single bottle 32213-2.5L which is physically identical with the same exact specifications.
The article number 32213-4X2.5L-M will be discontinued. Please order the single bottle 32213-2.5L-M which is physically identical with the same exact specifications.
The article number 32213-4X5L will be discontinued. Please order the single bottle 32213-5L which is physically identical with the same exact specifications.
The article number 32213-6X1L will be discontinued. Please order the single bottle 32213-1L which is physically identical with the same exact specifications.

Safety Information

• Pictograms: GHS02,GHS06,GHS08
• Signal Word: Danger
• Hazard Codes: H225,H301 + H311 + H331,H370
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1
• Target Organs: Eyes,Central nervous system
• Storage Class: 3 - Flammable liquids
• Flash Point (°F): 49.5 °F - closed cup
• Flash Point (°C): 9.7 °C - closed cup
• Precautionary Statements: P210 - P233 - P280 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P311