34875

tert-Butyl methyl ether

suitable for HPLC, ≥99.8%

• Synonym(s): MTBE, Methyl tert-butyl ether
• Linear Formula: (CH₃)₃COCH₃
• CAS Number: 1634-04-4
• Molecular Weight: 88.15
• UNSPSC Code: 41116105
• NACRES: NA.07
• PubChem Substance ID: 329755082
• EC Number: 216-653-1
• Beilstein/REAXYS Number: 1730942
• MDL number: MFCD00008812
• Assay: ≥99.8%
• Grade: HPLC grade
• Technique(s): HPLC: suitable
• Bp: 55-56 °C (lit.)
• Vapor pressure: 4.05 psi

Properties

• grade: HPLC grade
• Quality Segment: 100
• vapor density: 3.1 (vs air)
• vapor pressure: 4.05 psi
• assay: ≥99.8%
• form: liquid
• autoignition temp.: 705 °F
• expl. lim.: 15.1 %
• technique(s): HPLC: suitable
• impurities: ≤0.0005% non-volatile matter, ≤0.0005% peroxides (as H₂O₂), ≤0.002% free acid (as CH₃COOH), ≤0.01% water (Karl Fischer)
• color: APHA: ≤10
• transmittance: 220 nm, ≥40%, 250 nm, ≥80%, 260 nm, ≥90%, 290 nm, ≥99%
• refractive index: n20/D 1.369 (lit.)
• bp: 55-56 °C (lit.)
• mp: -110 °C
• density: 0.74 g/mL at 25 °C (lit.)
• UV absorption: λ: 210 nm A_max: ≤1.0, λ: 220 nm A_max: ≤0.40, λ: 250 nm A_max: ≤0.10, λ: 260 nm A_max: ≤0.05, λ: 300 nm A_max: ≤0.005, λ: 400 nm A_max: ≤0.005
• SMILES string: COC(C)(C)C
• application(s): food and beverages
• InChI: 1S/C5H12O/c1-5(2,3)6-4/h1-4H3
• InChI key: BZLVMXJERCGZMT-UHFFFAOYSA-N

Description

General description

tert-Butyl methyl ether (methyl tert-butyl ether, MTBE) is a gasoline additive. Its oxidative degradation by propane-oxidizing bacterial strains has been tested.[1] Kinetic studies of its heat-assisted persulfate oxidation at various pH, temperature, oxidant concentration and ionic strength levels suggests that reaction exhibits a pseudo-first-order decay model.[2]

Application

tert-Butyl methyl ether (methyl tert-butyl ether, MTBE) has been used in the isolation and quantitative determination of carotenes and xanthophylls from Capsicum annum pericarp extracts by HPLC.

Other Notes

Important notice

• The article number 34875-4X2.5L will be discontinued. Please order the single bottle 34875-2.5L which is physically identical with the same exact specifications.
• The article number 34875-6X1L will be discontinued. Please order the single bottle 34875-1L which is physically identical with the same exact specifications.

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Safety Information

• pictograms: GHS02,GHS07
• signalword: Danger
• hcodes: H225,H315
• pcodes: P210 - P233 - P240 - P241 - P242 - P303 + P361 + P353
• Hazard Classifications: Flam. Liq. 2 - Skin Irrit. 2
• Storage Class: 3 - Flammable liquids
• wgk: WGK 1
• flash_point_f: -18.4 °F - closed cup
• flash_point_c: -28 °C - closed cup