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366374

Sigma-Aldrich

Zinc chloride solution

0.5 M in THF

Linear Formula:
ZnCl2
CAS Number:
Molecular Weight:
136.30
MDL number:
PubChem Substance ID:
NACRES:
NA.55

form

liquid

Quality Level

concentration

0.5 M in THF
470-600 mmol/L (silver nitrate titration)

density

0.948 g/mL at 25 °C

SMILES string

Cl[Zn]Cl

InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

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General description

Zinc chloride solution is a colorless liquid that contains zinc chloride dissolved in THF. Its synthesis has been reported.

Application

Zinc chloride solution was used in the synthesis of the ferrocenylarenes.
It may be used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.

Packaging

100, 800 mL in Sure/Seal™

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-4.0 °F - closed cup

Flash Point(C)

-20 °C - closed cup

Certificate of Analysis

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Certificate of Origin

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