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383090

Sigma-Aldrich

Ammonium cerium(IV) sulfate dihydrate

ACS reagent, ≥94%

Synonym(s):

Ceric ammonium sulfate, Cerium(IV) ammonium sulfate

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About This Item

Linear Formula:
Ce(NH4)4(SO4)4 · 2H2O
CAS Number:
Molecular Weight:
632.55
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NB.24

grade

ACS reagent

Quality Level

assay

≥94%

form

powder or crystals

reaction suitability

reagent type: catalyst
core: cerium

impurities

≤0.05% insol. dil. H2SO4

mp

130 °C (lit.)

anion traces

phosphate (PO43-): ≤0.03%

cation traces

Fe: ≤0.01%

SMILES string

N.N.N.N.O.O.[Ce+4].OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O

InChI

1S/Ce.4H3N.4H2O4S.2H2O/c;;;;;4*1-5(2,3)4;;/h;4*1H3;4*(H2,1,2,3,4);2*1H2/q+4;;;;;;;;;;/p-4

InChI key

VCNAMBGKEDPVGQ-UHFFFAOYSA-J

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General description

Ammonium cerium(IV) sulfate dehydrate is a cerium salt widely used in the volumetric analysis.

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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[figure: see text] A novel benzyloxyaniline linker that uses ceric ammonium nitrate (CAN) as a cleavage reagent is described. Its application in the solid-phase synthesis of N-unsubstituted beta-lactams and secondary amides furnishes compounds in moderate to excellent yield (45-91%) and

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