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MilliporeSigma

467901

Supelco

Nickel(II) sulfate hexahydrate

≥99.99% trace metals basis

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50 G
$147.00

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About This Item

Linear Formula:
NiSO4 · 6H2O
CAS Number:
Molecular Weight:
262.85
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.55
Assay:
≥99.99% trace metals basis
Form:
solid

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vapor density

2.07 (vs air)

Quality Level

description

for inorganic trace analysis

assay

≥99.99% trace metals basis

form

solid

impurities

≤0.002% N compounds
≤0.005% insolubles
<100 ppm total metallic impurities

anion traces

chloride (Cl-): ≤0.001%

cation traces

Ca: ≤0.005%
Co: ≤0.002%
Cu: ≤0.005%
Fe: ≤0.001%
K: ≤0.01%
Mg: ≤0.005%
Mn: ≤0.002%
Na: ≤0.05%

SMILES string

O.O.O.O.O.O.[Ni++].[O-]S([O-])(=O)=O

InChI

1S/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2

InChI key

RRIWRJBSCGCBID-UHFFFAOYSA-L

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1 of 4

This Item
939331227676N4882
form

solid

form

powder or crystals

form

crystals

form

powder or crystals

assay

≥99.99% trace metals basis

assay

≥99.9% trace metals basis, 98-102% (EDTA, complexometric)

assay

≥98%

assay

98.0-102.0% (EDTA titration)

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

grade

for inorganic trace analysis

grade

-

grade

ACS reagent

grade

-

impurities

≤0.002% N compounds, <100 ppm total metallic impurities, ≤0.005% insolubles

impurities

≤1000 ppm trace metals basis

impurities

≤0.002% N compounds, ≤0.005% insolubles

impurities

-

cation traces

Ca: ≤0.005%, Cu: ≤0.005%, K: ≤0.01%, Mn: ≤0.002%, Co: ≤0.002%, Mg: ≤0.005%

cation traces

Al: <50 ppm, Ca: <50 ppm, Co: <50 ppm, Cu: <50 ppm, Fe: <50 ppm, K: <50 ppm, Mg: <50 ppm, Na: <50 ppm, Pb: <50 ppm, Zn: <50 ppm

cation traces

Ca: ≤0.005%, Co: ≤0.002%, Cu: ≤0.005%, Fe: ≤0.001%, K: ≤0.01%, Mg: ≤0.005%, Mn: ≤0.002%, Na: ≤0.05%

cation traces

Fe: ≤0.001%

General description

Nickel (II) sulfate hexahydrate (NiSO4·6H2O), commonly called retgersite, is a naturally occurring enantiomorphic mineral.[1] It crystallizes in the monoclinic space group C2/c.[2] Crystal structure of its various polymorphic forms have been investigated.[3] The chiral nickel sulfate hexahydrate has been reported to induce asymmetric autocatalysis.[1] The thermal degradation behavior of nickel(II) sulfate(VI) hexahydrate in air and helium atmosphere has been studied using thermogravimetry (TG) and X-ray powder diffraction (XRD).[4]

Application


  • Improvement of ion chromatography with ultraviolet photometric detection and comparison with conductivity detection for the determination of serum cations.: This study explores advanced ion chromatography techniques for analyzing serum cations, where Nickel(II) sulfate hexahydrate may be used as a standard or in method development. The research compares ultraviolet photometric detection with conductivity detection, enhancing analytical methods for precise cation analysis in various samples, which can be crucial for environmental and clinical chemistry (Shintani H, 1985).

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

target_organs

Respiratory Tract

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Asymmetric induction by retgersite, nickel sulfate hexahydrate, in conjunction with asymmetric autocatalysis.
Matsumoto A, et al.
New. J. Chem., 39(9), 6742-6745 (2015)
Structure of monoclinic nickel (II) sulfate hexahydrate.
Gerkin RE and Reppart WJ.
Acta Crystallographica Section C, Crystal Structure Communications, 44(8), 1486-1488 (1988)
Mechanism and kinetics of thermal decomposition of nickel (II) sulfate (VI) hexahydrate.
Tomaszewicz E and Kotfica M.
Journal of Thermal Analysis and Calorimetry, 77(1), 25-31 (2004)
Polymorphism of nickel sulfate hexahydrate.
Angel RJ and Finger LW.
Acta Crystallographica Section C, Crystal Structure Communications, 44(11), 1869-1873 (1988)
Xiaohua Xu et al.
Particle and fibre toxicology, 9, 40-40 (2012-11-07)
It has been well recognized that toxicity of fine ambient air particulate matter (PM(2.5)) may depend on its chemical constituents, including components such as soluble metals that may theoretically exert distinctive effects. We have recently demonstrated an important effect of

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