Skip to Content
MilliporeSigma

62580

Lithium perchlorate

purum p.a., ≥98.0% (calc. based on dry substance, T), powder

Slide 1 of 1
Sign In to View Organizational & Contract Pricing.

Select a Size

100 G

$215.00

500 G

$645.00

$215.00

Check Cart for Availability
Request a Bulk Order
Ships Every 4 weeks

About This Item

Linear Formula:
LiClO4
CAS Number:
7791-03-9
Molecular Weight:
106.39
NACRES:
NA.21
PubChem Substance ID:
329759742
UNSPSC Code:
12352302
EC Number:
232-237-2
MDL number:
MFCD00011079
Assay:
≥98.0% (calc. based on dry substance, T)
Form:
powder
Solubility:
alcohol: soluble(lit.), water: soluble(lit.)

Key Documents

View All Documentation

Skip To

Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

InChI key

MHCFAGZWMAWTNR-UHFFFAOYSA-M

InChI

1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1

SMILES string

[Li+].[O-]Cl(=O)(=O)=O

grade

purum p.a.

assay

≥98.0% (calc. based on dry substance, T)

form

powder

reaction suitability

reagent type: oxidant

impurities

≤3% water

pH

6.0-9.5 (25 °C, 106.4 g/L)

mp

236 °C (lit.)

solubility

alcohol: soluble(lit.), water: soluble(lit.)

anion traces

chloride (Cl-): ≤50 mg/kg, sulfate (SO42-): ≤200 mg/kg

cation traces

Ca: ≤100 mg/kg, Cd: ≤50 mg/kg, Co: ≤50 mg/kg, Cu: ≤50 mg/kg, Fe: ≤50 mg/kg, K: ≤500 mg/kg, Na: ≤100 mg/kg, Ni: ≤50 mg/kg, Pb: ≤50 mg/kg, Zn: ≤50 mg/kg

Quality Level

200

Looking for similar products? Visit Product Comparison Guide

Related Categories

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
43156793196918-1605
Lithium perchlorate purum p.a., ≥98.0% (calc. based on dry substance, T), powder

Sigma-Aldrich

62580

Lithium perchlorate

Lithium perchlorate 99.99% trace metals basis

Sigma-Aldrich

431567

Lithium perchlorate

Lithium perchlorate ≥99.9% trace metals basis

Sigma-Aldrich

931969

Lithium perchlorate

Lithium perchlorate SAJ special grade, ≥99.0%

Sigma-Aldrich

18-1605

Lithium perchlorate

form

powder

form

granular

form

powder

form

crystalline

assay

≥98.0% (calc. based on dry substance, T)

assay

99.99% trace metals basis

assay

≥99.9% trace metals basis

assay

≥99.0%

solubility

alcohol: soluble(lit.), water: soluble(lit.)

solubility

H2O: 106.4 g/L at 20 °C

solubility

H2O: 59.8 g/dL at 25 °C

solubility

-

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

-

grade

purum p.a.

grade

-

grade

-

grade

-

impurities

≤3% water

impurities

≤0.005% insolubles, <100 ppm total metallic impurities

impurities

≤1000 ppm (trace metals analysis)

impurities

-

General description

Lithium perchlorate (LiClO4) is a colorless lithium salt. Upon crystallization from its aqueous solution, it affords lithium perchlorate trihydrate (LiClO4.3H2O). It can be synthesized by reacting lithium chloride with perchloric acid.[1]

Application

Lithium perchlorate (LiClO4) may be used as a catalyst in the synthesis of bis(indolyl)methanes[2] and in the Baylis-Hillman coupling reaction of α,β-unsaturated carbonyl compounds with aldehydes.[3]

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1A - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
BCCN9751
BCCM4132
BCCH2082
BCCH1636
BCCH6373

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Lithium perchlorate-accelerated Baylis-Hillman reactions.
Kawamura M and Kobayashi S.
Tetrahedron Letters, 40(8), 1539-1542 (1999)
Lithium perchlorate catalyzed reactions of indoles: An expeditious synthesis of bis (indolyl) methanes.
Yadav JS, et al.
Synthesis, 2001(5), 0783-0787 (2001)
Jun-Sik Seo et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(8), 1747-1756 (2002-08-09)
Vibrational characteristics of CD3CN solutions of LiClO4 and NaClO4 have been studied by means of infrared and Raman spectroscopy. Blue shifts of 22 and 11 cm(-1) of the v2 C[triple bond]N stretch are observed resulting from interaction of CD3CN with
Increased T(c) in electrolyte-gated cuprates.
Anoop Singh Dhoot et al.
Advanced materials (Deerfield Beach, Fla.), 22(23), 2529-2533 (2010-05-07)
Electrochemical enol ether/olefin cross-metathesis in a lithium perchlorate/nitromethane electrolyte solution.
Teppei Miura et al.
Angewandte Chemie (International ed. in English), 45(9), 1461-1463 (2006-01-28)
View All Related Papers

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service