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63102

Magnesium perchlorate

puriss., free-flowing powder, ≥99.0% (calc. based on dry substance, KT)

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500 G

$329.00

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About This Item

Linear Formula:
Mg(ClO4)2
CAS Number:
Molecular Weight:
223.21
UNSPSC Code:
12352300
PubChem Substance ID:
EC Number:
233-108-3
MDL number:
Assay:
≥99.0% (calc. based on dry substance, KT)
Form:
free flowing powder

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InChI key

MPCRDALPQLDDFX-UHFFFAOYSA-L

InChI

1S/2ClHO4.Mg/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2

SMILES string

[Mg++].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O

grade

puriss.

assay

≥99.0% (calc. based on dry substance, KT)

form

free flowing powder

quality

free-flowing powder

impurities

≤8% water

storage temp.

room temp

Quality Level

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1 of 4

This Item
63095222283309303
form

free flowing powder

form

powder or chunks

form

flakes, powder, chunks or granules

form

crystalline

assay

≥99.0% (calc. based on dry substance, KT)

assay

≥98.0% (calc. based on dry substance, KT)

assay

-

assay

99%

Quality Level

200

Quality Level

200

Quality Level

200

Quality Level

100

grade

puriss.

grade

-

grade

-

grade

-

impurities

≤8% water

impurities

≤0.005 meq/g free acid (as HClO4), ≤0.025 meq/g free alkali (as MgO), ≤8% water

impurities

≤0.005 meq/g Titr. free acid, ≤0.025 meq/g Titr. base

impurities

-

quality

free-flowing powder

quality

-

quality

-

quality

-

General description

Magnesium perchlorate (Mg(ClO4)2) is widely used as drying agent for gases. It can remove water from gases (with no organic contaminants) at the rate of 0.001mgwater/l.[1]

Application

Magnesium perchlorate (Mg(ClO4)2) may be employed as a catalyst in the following studies:
  • Preparation of a-aminophosphonates.[2]
  • Enantioselective Diels-Alder reaction between cyclopentadiene and 3-acryloyl-1,3-oxazolin-2-one.[3]
  • Preparation of imines and phenylhydrazones.[4]
  • Protection of alcohols in the form of t-butyl ethers.[5]
filler for drying tubes (especially for elemental analysis)

pictograms

Flame over circleExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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The first enantioselective synthesis of both Diels-Alder enantiomers with the same bis (oxazoline)-magnesium perchlorate chiral catalyst.
Desimoni G, et al.
Tetrahedron Letters, 37(17), 3027-3030 (1996)
Magnesium perchlorate as an efficient catalyst for the synthesis of imines and phenylhydrazones.
Chakraborti AK, et al.
Tetrahedron Letters, 45(41), 7641-7644 (2004)
Eagleson M.
Concise Encyclopedia Chemistry, 343-343 (1994)
K Miyake et al.
Photochemistry and photobiology, 58(5), 631-636 (1993-11-01)
We have investigated the photosensitized monomerization of the cis,syn-cyclobutane dimer of 1,3-dimethylthymine using riboflavin tetraacetate and a 5-deazaflavin derivative as photosensitizer. Although little monomerization of the dimer is induced by photoexcitation of the flavins in the absence of any additives
T Theophanides
Magnesium research, 9(4), 259-262 (1996-12-01)
The interaction of Mg2+ cations in biological systems is studied by using nucleic acid bases as the biological system. Magnesium salts, such as, MgCl2 6H2O, MgSO4. 7H2O and Mg(ClO4). XH2O have been employed in order to compare their complexation with

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