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MilliporeSigma

650552

Hexane

≥95%, HPLC Plus, for residue analysis, suitable for gas chromatography (GC) and HPLC, suitable for EPA 1613, EPA ACB B21-02, EPA OTM-45, and EPA ACB B23-05b

Synonym(s):

n-Hexane

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1 L

$186.00

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$411.00

6 X 1 L

$844.00

4 X 4 L

$1,190.00

$186.00


Estimated to ship onDecember 08, 2025Details


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About This Item

Linear Formula:
CH3(CH2)4CH3
CAS Number:
Molecular Weight:
86.18
Beilstein/REAXYS Number:
1730733
EC Number:
MDL number:
UNSPSC Code:
12190000
PubChem Substance ID:
NACRES:
NA.06
Grade:
HPLC Plus
Assay:
≥95%
Technique(s):
HPLC: suitable
gas chromatography (GC): suitable
Application(s):
food and beverages
Bp:
69 °C (lit.)
Vapor pressure:
256 mmHg ( 37.7 °C)
5.2 psi ( 37.7 °C)
~132 mmHg ( 20 °C)

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Product Name

Hexane, HPLC Plus, for HPLC, GC, and residue analysis, ≥95%

grade

HPLC Plus

Quality Level

agency

suitable for EPA 1613
suitable for EPA ACB B21-02
suitable for EPA ACB B23-05b
suitable for EPA OTM-45

vapor density

~3 (vs air)

vapor pressure

256 mmHg ( 37.7 °C)
5.2 psi ( 37.7 °C)
~132 mmHg ( 20 °C)

assay

≥95%

form

liquid

autoignition temp.

453 °F

expl. lim.

7.7 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

impurities

≤ 1.0 ppb Fluorescence (quinine) at 365 nm
<0.01% water

evapn. residue

<0.0001%

halogenated residue

<10 ng/L (as heptachlor epoxide)

refractive index

n20/D 1.375 (lit.)

pH

7

bp

69 °C (lit.)

mp

−95 °C (lit.)

solubility

ethanol: soluble(lit.)

density

0.659 g/mL at 25 °C (lit.)

UV absorption

λ: 195 nm Amax: 1.00
λ: 200 nm Amax: 0.50
λ: 210 nm Amax: 0.20
λ: 220 nm Amax: 0.05
λ: 250 nm Amax: 0.01
λ: 280-400 nm Amax: 0.005

suitability

suitable for residue analysis

application(s)

food and beverages

SMILES string

CCCCCC

InChI

1S/C6H14/c1-3-5-6-4-2/h3-6H2,1-2H3

InChI key

VLKZOEOYAKHREP-UHFFFAOYSA-N

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This Item
67539334859208752
technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable

technique(s)

-

application(s)

food and beverages

application(s)

-

application(s)

food and beverages

application(s)

-

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

assay

≥95%

assay

≥95%

assay

≥97.0% (GC)

assay

≥95%

grade

HPLC Plus, for residue analysis

grade

HPLC Plus, for residue analysis

grade

-

grade

Laboratory Reagent

solubility

ethanol: soluble(lit.)

solubility

ethanol: soluble(lit.)

solubility

-

solubility

-

General description

Hexane (n-hexane) is an alkane, that can be obtained from petroleum by distillation. It can also be produced by electrolyzing the potassium butyrate solution. It is widely employed organic solvent for the dissolution and isolation of fats and oils.[1] Its thermodynamic properties[2] and kinetics of thermal decomposition have been studied over a range of temperature.[3] A study on the zeolite supported platinum catalyzed isomerization and aromatization of n-hexane has been reported.[4] Its removal from hexane contaminated air streams using vapor phase biological reactor (VPBR) immobilized with hexane-degrading Aspergillus niger strain has been studied.[5] The metabolism of n-hexane forms 2,5-hexanedione (2,5-HD), which is reported to induce neurotoxicity.[6]

Application

Hexane may be used in the following studies:
  • Preparation of graft-copolymer chains of poly-(dimethylsiloxane)-g-poly(methyl methacrylate).[7]
  • GC/MS characterization of essential oils isolated from various origins.[8]
  • As solvent for the preparation of samples and standards during chromatographic studies.[9]
  • To extract free and total gossypol in combination with acetone from cottonseed flakes.[10]
Suitable for HPLC, spectrophotometry, environmental testing

Packaging

M-Bottle for Solvents
As a global leader in lab reagents, we are constantly looking for new ways to optimize the safety of our products. The newly developed 4L solvent bottle design features advanced sealing technology that eliminates leaks to make the handling of solvents safer and more convenient than ever before.
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Other Notes

Discover LiChropur reagents ideal for HPLC or LC-MS analysis

signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 Inhalation - STOT SE 3

target_organs

Central nervous system, Nervous system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-7.6 °F - closed cup

flash_point_c

-22 °C - closed cup


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Cottonseed extraction with mixtures of acetone and hexane.
Kuk MS, et al.
Journal of the American Oil Chemists' Society, 82(8), 609-612 (2005)
Thermodynamic properties of n-hexane.
Grigoryev BA, et al.
International Journal of Thermophysics, 9(3), 439-452 (1988)
The thermal decomposition of n-hexane.
Ebert KH, et al.
International Journal of Chemical Kinetics, 15(5), 475-502 (1983)
VOCs removal from waste gases: gas-phase bioreactor for the abatement of hexane by Aspergillus niger.
Spigno G, et al.
Chemical Engineering Science, 58(3), 739-746 (2003)
Reforming of hexane with Pt/zeolite catalysts.
Dai LX, et al.
Catalysis Letters, 45(1-2), 107-112 (1997)

Related Content

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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