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88071

Sigma-Aldrich

meso-Tetraphenylporphyrin

BioReagent, suitable for fluorescence, ≥99.0% (HPLC)

Synonym(s):
5,10,15,20-Tetraphenylporphin, TPP
Empirical Formula (Hill Notation):
C44H30N4
CAS Number:
Molecular Weight:
614.74
Beilstein:
379542
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.32

product line

BioReagent

Quality Level

Assay

≥99.0% (HPLC)

form

crystals

impurities

≤0.5% chlorin

solubility

dichloromethane: soluble

fluorescence

λex 420 nm; λem 651 nm in toluene

suitability

suitable for fluorescence

storage temp.

−20°C

SMILES string

c1ccc(cc1)-c2c3ccc(n3)c(-c4ccccc4)c5ccc([nH]5)c(-c6ccccc6)c7ccc(n7)c(-c8ccccc8)c9ccc2[nH]9

InChI

1S/C44H30N4/c1-5-13-29(14-6-1)41-33-21-23-35(45-33)42(30-15-7-2-8-16-30)37-25-27-39(47-37)44(32-19-11-4-12-20-32)40-28-26-38(48-40)43(31-17-9-3-10-18-31)36-24-22-34(41)46-36/h1-28,45,48H/b41-33-,41-34-,42-35-,42-37-,43-36-,43-38-,44-39-,44-40-

InChI key

YNHJECZULSZAQK-LWQDQPMZSA-N

Gene Information

human ... TERT(7015)

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This Item
160997247367389404
assay

≥99.0% (HPLC)

assay

97%

assay

≥99%

assay

-

form

crystals

form

powder or crystals

form

crystalline powder

form

powder, crystals or chunks

solubility

dichloromethane: soluble

solubility

chloroform: 1 mg/mL, clear to opaque

solubility

toluene: 0.03 g/L, clear

solubility

-

fluorescence

λex 420 nm; λem 651 nm in toluene

fluorescence

-

fluorescence

-

fluorescence

-

suitability

suitable for fluorescence

suitability

-

suitability

-

suitability

-

General description

Tetraphenylporphyrin is a precipitation inhibitor.

Biochem/physiol Actions

Tetraphenylporphyrin serves as an efficient inhibitor for Mg and its alloys. It is mainly used as a porphyrin moiety, in the preparation of ligand and introduction of metal in porphyrin.

Analysis Note

In addition to the emission maximum at 651 nm, there is a lower maxima at 717 nm.

Other Notes

Sensitizer used for the photochemical generation of singlet oxygen

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Xavier C Ding et al.
PLoS neglected tropical diseases, 11(4), e0005516-e0005516 (2017-04-04)
The global prevalence of malaria has decreased over the past fifteen years, but similar gains have not been realized against Plasmodium vivax because this species is less responsive to conventional malaria control interventions aimed principally at P. falciparum. Approximately half
Corrosion inhibition of magnesium (Mg) alloys
Corrosion Prevention of Magnesium Alloys, 61-84 (2013)
Ken-ichiro Murata et al.
Proceedings of the National Academy of Sciences of the United States of America, 112(19), 5956-5961 (2015-04-29)
A liquid-liquid transition (LLT) in a single-component substance is an unconventional phase transition from one liquid to another. LLT has recently attracted considerable attention because of its fundamental importance in our understanding of the liquid state. To access the order
H. Leininger et al.
Chemische Berichte, 116, 681-681 (1983)
E.D. Mihelich et al.
The Journal of Organic Chemistry, 48, 4135-4135 (1983)

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