11324-U

Supelco

Carboxen® Adsorbent

matrix Carboxen® 564, 20-45 mesh, pack of 144 × 290 mg

NACRES:
SB.54

Quality Level

form

powder

packaging

pack of 144 × 290 mg

application(s)

LPLC: suitable

matrix

Carboxen® 564

matrix active group

carbon

particle size

20-45 mesh

pore size

~0.13 cm3/g mesoporosity
~0.14 cm3/g macroporosity
~0.24 cm3/g microporosity
~6-9 Å pore diameter

surface area

~400 m2/g

density

~0.61 g/mL (free fall density)

separation technique

reversed phase

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General description

A carbon molecular sieve (CMS) is the porous carbon skeletal framework that remains after pyrolysis of a polymeric precursor. These particles are:
  • Spherical (better packed bed performance than granular particles)
  • Hard and non-friable (pack well, will not break)
  • Highly porous (high surface areas)
  • Used for molecules with an analyte size relative to C2-C5 n-alkanes
  • Hydrophobic (can be used in high humidity environments)

Generally, CMS adsorbents offer greater relative adsorptive strength compared to spherical graphitized polymer carbon (SGPC) and graphitized carbon black (GCB) adsorbents. Our Carboxen products are a type of CMS adsorbent.
  • Have tapered pores, resulting in excellent thermodynamic properties for both adsorption and desorption (have the best thermodynamic performance of any adsorbents)
  • The surface chemistry can be tailored for specific target analytes

For more information about any of our specialty carbon adsorbents, please visit sigma-aldrich.com/carbon

Footnote

Pack of 144 ampules

Legal Information

Carboxen is a registered trademark of Sigma-Aldrich Co. LLC

RIDADR

NONH for all modes of transport

Certificate of Analysis

Certificate of Origin

Applications of Solid Phase Microextraction.
Pawliszyn J.
Science, 64-65 (1999)
B D Page et al.
Journal of chromatography. A, 873(1), 79-94 (2000-04-11)
The headspace solid-phase microextraction (HS-SPME) efficiencies from vegetable oil of the recently available Carboxen-poly(dimethylsiloxane) (PDMS) and divinylbenzene-Carboxen-PDMS fibres were found to be much greater than those of the PDMS fibre for a number of volatile contaminants. Using these Carboxen-based fibres...
Dawn M Chapman et al.
Journal of agricultural and food chemistry, 52(17), 5431-5435 (2004-08-19)
A rapid and automated solid phase microextraction (SPME) stable isotope dilution gas chromatography/mass spectrometry (GC-MS) method for 2-methoxy-3-isobutylpyrazine (MIBP) quantification in red wine was developed. Wines with 30% (w/v) NaCl and 2-methoxy-(2)H(3)-3-isobutylpyrazine internal standard were sampled with a 2 cm...
Shih-Wei Tsai et al.
Journal of chromatography. A, 991(1), 1-11 (2003-04-22)
The solid-phase microextraction (SPME) device was used as a time-weighted average (TWA) sampler for ethylene oxide. Carboxen/polydimethylsiloxane (CAR/PDMS) fiber was used and hydrogen bromide (HBr) was loaded onto the fiber. The SPME fiber assembly was then inserted into PTFE tubing...
Lucia Giordano et al.
Journal of chromatography. A, 1017(1-2), 141-149 (2003-10-31)
A new method was developed for the determination of 2-furfural (2-F) and 5-methylfurfural (5-MF), two products of Maillard reaction in vinegar, with head-space solid-phase microextraction (HS-SPME) coupled to gas chromatography-mass spectrometry (GC-MS). A divinylbenzene (DVB)/carboxen (CAR)/polydimethylsiloxane (PDMS) fibre was used...
Articles
Carbon Molecular sieves (CMS) are a versatile range of adsorbents that can be tailored for specific applications. Supelco® scientists have been synthesizing synthetic CMS carbons for several decades, starting from tailoring of the starting polymers/copolymers, to modifying the final properties of the subsequent CMS carbon.
Read More

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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