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Ryszard Dobrowolski et al.
Talanta, 113, 19-25 (2013-05-28)
A new analytical procedure for vanadium (V) determination in soils and sediments by the slurry sampling graphite furnace atomic absorption spectrometry (slurry sampling GFAAS) using the mixed permanent modifiers is described. Moreover, the comparison of action of the modifiers based...
Tang-Lin Liu et al.
Organic letters, 15(7), 1740-1743 (2013-03-15)
A novel method to desymmetrize meso-anhydrides into lactones via asymmetric hydrogenation catalyzed by the Ir-C3*-TunePhos complex has been developed. Various chiral lactones were synthesized with full conversion and excellent enantioselectivity under high reaction temperature.
Ikuo Sasaki et al.
Chemical communications (Cambridge, England), 49(68), 7546-7548 (2013-07-23)
Ir(I)-catalyzed C-H borylation of 1-cycloalkenecarboxylic derivatives with bis(pinacolato)diboron affords various alkenylboronates with functional groups in excellent yields. This reaction was also used in a one-pot borylation/Suzuki-Miyaura cross-coupling procedure.
Kaiyou Chen et al.
ChemSusChem, 6(4), 613-621 (2013-03-07)
High (≥95 % C) yields of n-hexane and n-pentane were obtained by hydrogenolysis of aqueous sorbitol and xylitol, respectively, at 413-443 K by using the Ir-ReOx /SiO2 catalyst combined with H-ZSM-5 as a cocatalyst and n-dodecane as a cosolvent. The...
Naser Pour Aryan et al.
Conference proceedings : ... Annual International Conference of the IEEE Engineering in Medicine and Biology Society. IEEE Engineering in Medicine and Biology Society. Annual Conference, 2012, 819-822 (2013-02-01)
Iridium is one of the main electrode materials for applications like neural stimulation. Iridium has a higher charge injection capacity when activated and transformed into AIROF (activated iridium oxide film) using specific electrical signals. Activation is not possible in stimulating...
Etienne Baranoff et al.
Chemical Society reviews, 33(3), 147-155 (2004-03-18)
In order to mimic the photosynthetic reaction centre and better understand photoinduced electron transfer processes, a family of compounds has been studied for the past 15 years. These are transition metal complexes, M(tpy)(2) where tpy is a 2,2':6',2" terpyridine based...
S Murahashi et al.
Accounts of chemical research, 33(4), 225-233 (2000-04-25)
The discovery of a new chemical reaction often leads to new applications and new chemical principles. Low-valent ruthenium and iridium hydride complexes are highly useful redox Lewis acid and base catalysts. Nitriles are activated by these catalysts and undergo reactions...
Mingxin Chang et al.
Organic letters, 15(17), 4354-4357 (2013-08-14)
A green method for chiral amine synthesis, the direct catalytic asymmetric reductive amination, was developed. Phenylhydrazide is an ideal nitrogen source for reductive amination. Molecular sieves play dual roles in this reaction. They help to remove H2O to form imine...
Houhua Li et al.
Organic letters, 15(24), 6170-6173 (2013-11-14)
The iridium-catalyzed diastereo- and regioselective isomerization of primary allylic alcohols using Crabtree's catalyst or sterically modified analogs is reported. The importance of the size of the substituents on either the substrates or the catalysts has been rationalized by linear free...
Rakesh Kumar Gupta et al.
Inorganic chemistry, 52(7), 3687-3698 (2013-03-13)
The synthesis of four novel heteroleptic dipyrrinato complexes [(η(6)-arene)RuCl(2-pcdpm)] (η(6)-arene = C6H6, 1; C10H14, 2) and [(η(5)-C5Me5)MCl(2-pcdpm)] (M = Rh, 3; Ir, 4) containing a new chelating ligand 4-(2-methoxypyridyl)-phenyldipyrromethene (2-pcdpm) have been described. The complexes 1-4 have been fully characterized...
Veronica Marin et al.
Chemical Society reviews, 36(4), 618-635 (2007-03-28)
The need for novel materials with luminescent properties and advanced processing features requires reliable and reproducible synthetic routes for the design of suitable materials, such as e.g. polypyridyl ruthenium(II) and iridium(III)-containing polymers. The most popular ligand for those purposes is...
Yasuyuki Hirata et al.
Physical review letters, 110(18), 187402-187402 (2013-05-21)
The structural, electronic, and optical properties of pyrochlore-type Pb(2)Ir(2)O(6)O(0.55)('), which is a metal without spatial inversion symmetry at room temperature, were investigated. Structural analysis revealed that the structural distortion relevant to the breakdown of the inversion symmetry is dominated by...
Evelia Rasolofonjatovo et al.
Organic letters, 15(18), 4698-4701 (2013-09-10)
Iridium dimer complexes were found to catalyze the [3 + 2] cycloaddition reaction of azides with bromoalkynes, yielding 1,5-disubstituted 4-bromo-1,2,3-triazoles in reasonable to excellent yields under mild conditions. The reaction offers a direct route to new 1,4,5-trisubstituted triazoles.
Nicolas P E Barry et al.
Chemical Society reviews, 41(8), 3264-3279 (2012-02-07)
This review describes how the incorporation of dicarba-closo-dodecarboranes into half-sandwich complexes of ruthenium, osmium, rhodium and iridium might lead to the development of a new class of compounds with applications in medicine. Such a combination not only has unexplored potential...
Dik-Lung Ma et al.
PloS one, 8(2), e55751-e55751 (2013-03-05)
A cell permeable cyclometalated iridium(III) complex has been developed as a phosphorescent probe for cell imaging. The iridium(III) solvato complex [Ir(phq)2(H2O]2)] preferentially stains the cytoplasm of both live and dead cells with a bright luminescence.
Artin Petrossians et al.
Conference proceedings : ... Annual International Conference of the IEEE Engineering in Medicine and Biology Society. IEEE Engineering in Medicine and Biology Society. Annual Conference, 2012, 727-730 (2013-02-01)
An electrodeposition technique was applied for fabrication of dense platinum-iridium alloy nanowires as interconnect structures in hermetic microelectronic packaging to be used in implantable devices. Vertically aligned arrays of platinum-iridium alloy nanowires with controllable length and a diameter of about...
Thomas Niederhauser et al.
IEEE transactions on bio-medical engineering, 60(9), 2576-2584 (2013-05-08)
The emerging application of long-term and high-quality ECG recording requires alternative electrodes to improve the signal quality and recording capability of surface skin electrodes. The esophageal ECG has the potential to overcome these limitations but necessitates novel recorder and lead...
Jesús M Fernández-Hernández et al.
Inorganic chemistry, 52(4), 1812-1824 (2013-02-07)
A series of blue and blue-green emitters based on neutral bis- and tris-cyclometalated Ir(III) complexes with 1-benzyl-4-(2,6-difluorophenyl)-1H-1,2,3-triazole (dfptrBn) as cyclometalating ligand is reported. The bis-cyclometalated complexes of the type [Ir(dfptrBn)(2)(L(^)X)] with different ancillary ligands, L(^)X = picolinate (pic) (2) or...
I Haiduc et al.
In vivo (Athens, Greece), 3(4), 285-293 (1989-07-01)
Recent results on the antitumor activity of organometallic compounds of rhodium, iridium, copper and gold are reviewed. Coordination compounds of some organic ligands are also briefly mentioned. The most promising seem to be copper and gold complexes which exhibited remarkable...
Paolo Tosatti et al.
Organic & biomolecular chemistry, 10(16), 3147-3163 (2012-03-13)
Since their discovery in 1997, iridium-catalysed asymmetric allylic substitutions have been developed into a broadly applicable tool for the synthesis of chiral building blocks via C-C and C-heteroatom bond formation. The remarkable generality of these reactions and the high levels...
Angèle Monney et al.
Dalton transactions (Cambridge, England : 2003), 42(16), 5655-5660 (2013-02-27)
The Nδ,Nε-dimethylated histidinium salt (His*) was tethered to oligopeptides and metallated to form Ir(III) and Rh(I) NHC complexes. Peptide-based histidylidene complexes containing only alanine, Ala-Ala-His*-[M] and Ala-Ala-Ala-His*-[M] were synthesised ([M] = Rh(cod)Cl, Ir(Cp*)Cl2), as well as oligopeptide complexes featuring a...
Yuyang Zhou et al.
Chemical communications (Cambridge, England), 49(31), 3230-3232 (2013-03-14)
Five iridium(III) complexes with two N-heterocyclic carbene (NHC) ligands and an ancillary ligand have been designed and successfully synthesized. With multicolor photoluminescence and low toxicity, these carbene complexes were tested, for the first time, as living cell imaging reagents and...
Le Guo et al.
Organic letters, 15(5), 1144-1147 (2013-02-16)
The first α-alkylation of unactivated amides with primary alcohols is described. An effective and robust iridium pincer complex has been developed for selective α-alkylation of tertiary and secondary acetamides involving a "borrowing hydrogen" methodology. The method is compatible with alcohols...
V Guritanu et al.
Physical review letters, 109(24), 247207-247207 (2013-02-02)
We have investigated the optical conductivity of the prominent valence-fluctuating compounds EuIr(2)Si(2) and EuNi(2)P(2) in the infrared energy range to get new insights into the electronic properties of valence-fluctuating systems. For both compounds, we observe upon cooling the formation of...
Zhe Hu et al.
Conference proceedings : ... Annual International Conference of the IEEE Engineering in Medicine and Biology Society. IEEE Engineering in Medicine and Biology Society. Annual Conference, 2012, 2788-2791 (2013-02-01)
Activated Iridium Oxide Film (AIROF) microelectrodes are regarded as advantage for stimulation of neural tissue owing to their superior charge injection capabilities, as compared to other noble-metal based electrodes. Including AIROF electrodes within an implantable neural stimulator can be challenging...
Shiguang Pan et al.
Organic letters, 15(8), 1902-1905 (2013-04-02)
A cationic Ir(I) complex-catalyzed O-to-N-alkyl migration in 2-alkoxypyridines bearing a secondary alkyl group on the oxygen atom by C-O bond cleavage is described. The present transformation gave various N-alkylpyridones in moderate to good yields. The addition of sodium acetate played...
Steve Po-Yam Li et al.
Biomaterials, 34(30), 7519-7532 (2013-07-16)
We present a new class of phosphorescent cyclometalated iridium(III) polypyridine poly(ethylene glycol) (PEG) complexes [Ir(N(^)C)2(bpy-CONH-PEG)](PF6) (bpy-CONH-PEG = 4-(N-(2-(ω-methoxypoly-(1-oxapropyl))ethyl)aminocarbonyl)-4'-methyl-2,2'-bipyridine, number average molecular weight (Mn) = 5272.23, weight average molecular weight (Mw) = 5317.38, polydispersity index (PDI) = 1.009; HN(^)C = 2-phenylpyridine...
Hye Rim Park et al.
Journal of nanoscience and nanotechnology, 13(5), 3441-3445 (2013-07-19)
According to a recent report, the organic light-emitting diodes (OLEDs) using the iridium complexes of coumarin derivatives as emissive dopants are highly efficient and stable. Unlike the other Ir(III) phopsphorescent dopants, these coumarin-based Ir(III) complexes can effectively trap and transport...
M Y Zhang et al.
Optics express, 21 Suppl 1, A173-A178 (2013-02-15)
We have investigated the transport characteristics of red phosphorescent dye bis(1-(phenyl)isoquinoline) iridium (III) acetylanetonate (Ir(piq)₂acac) doped 4,4',4"-tri(N-carbazolyl)triphenylamine (TCTA), and found that the increasing doping ratio was facilitated to improve the ability of hole transporting. A high color rendering index (CRI)...
Matthew R Kelley et al.
Inorganic chemistry, 52(5), 2564-2580 (2013-02-21)
A series of seven [Ir{ArNC(NR2)NAr}(cod)] complexes (1a-1g; where R = Me or Et; Ar = Ph, 4-MeC6H4, 4-MeOC6H4, 2,6-Me2C6H3, or 2,6-(i)Pr2C6H3; and cod = 1,5-cyclooctadiene) were synthesized by two different methods from the neutral guanidines, ArN═C(NR2)NHAr, using either MeLi and...
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