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Kevin Mason et al.
Dalton transactions (Cambridge, England : 2003), 41(29), 8777-8785 (2012-04-11)
Strapping two salicylaldoxime units together with aliphatic α,Ω-aminomethyl links in the 3-position gives ligands which allow the assembly of the polynuclear complexes [Fe(7)O(2)(OH)(6)(H(2)L1)(3)(py)(6)](BF(4))(5)·6H(2)O·14MeOH (1·6H(2)O·14MeOH), [Fe(6)O(OH)(7)(H(2)L2)(3)](BF(4))(3)·4H(2)O·9MeOH (2·4H(2)O·9MeOH) and [Mn(6)O(2)(OH)(2)(H(2)L1)(3)(py)(4)(MeCN)(2)](BF(4))(5)(NO(3))·3MeCN·H(2)O·5py (3·3MeCN·H(2)O·5py). In each case the metallic skeleton of the cluster is based...
Anodic-stripping voltammetry of metal complexes in non-aqueous media after extraction: determination of copper with salicylaldoxime.
J Aznárez et al.
The Analyst, 111(6), 619-624 (1986-06-01)
Filippo Minutolo et al.
Journal of medicinal chemistry, 52(3), 858-867 (2009-01-09)
The bioisosteric replacement of the phenol ring, a signature functional group of most estrogen receptor (ER) ligands, with a hydrogen-bonded pseudocyclic ring, led to the development of a novel class of nonsteroidal ER-ligands based on a salicylaldoxime template. A series...
K P Mull et al.
Clinical and experimental pharmacology & physiology, 26(12), 964-969 (2000-01-08)
1. The effects of the K+ channel opener diazoxide and the oxime-containing Ca2+ and K+ channel blocker salicylaldoxime were tested in canine cardiac Purkinje tissue. 2. Both drugs shortened action potential duration (APD). For salicylaldoxime (0.1-1.0 mmol/L), the reductions in...
Hui-Lien Tsai et al.
Inorganic chemistry, 51(24), 13171-13180 (2012-12-12)
Two Mn(4) single-molecule-magnet (SMM)-based coordination polymers, {[Mn(4)O(salox)(3)(N(3))(3)(DMF)(2)(H(2)O)(dpp)]·0.5MeOH}(n) (1·0.5MeOH; H(2)salox = salicylaldoxime; dpp = 1,3-di-4-pyridylpropane; DMF = N,N-dimethylformamide) and {[Mn(4)O(Me-salox)(3)(N(3))(3)(dpp)(1.5)]·1.5Et(2)O}(n) (2·1.5Et(2)O; Me-H(2)salox = hydroxyphenylethanone oxime), are self-assembled from Mn(ClO(4))(2)·6H(2)O/H(2)salox and Mn(ClO(4))(2)·6H(2)O/Me-H(2)salox systems with dpp and NaN(3) in DMF/MeOH, respectively. Both compounds...
Ngoc T Bui et al.
Nature communications, 11(1), 3947-3947 (2020-08-10)
Herein, we present a scalable approach for the synthesis of a hydrogen-bonded organic-inorganic framework via coordination-driven supramolecular chemistry, for efficient remediation of trace heavy metal ions from water. In particular, using copper as our model ion of interest and inspired...
Chandrika Ravindran Preetha et al.
Environmental science & technology, 40(9), 3070-3074 (2006-05-25)
Major quantities of uranium find use as nuclear fuel in nuclear power reactors. In view of the extreme toxicity of uranium and consequent stringent limits fixed by WHO and various national governments, it is essential to remove uranium from nuclear...
D D Ourth et al.
Developmental and comparative immunology, 6(1), 75-85 (1982-01-01)
Fresh channel catfish (Ictalurus punctatus) serum from unimmunized catfish exhibited 100% bactericidal activity against Salmonella paratyphi. Components responsible for bactericidal activity could be absorbed from the fresh catfish serum with S. paratyphi. The bactericidal system of the fresh catfish serum...
R B Singh et al.
Talanta, 26(6), 425-444 (1979-06-01)
The uses of oximes as spectrophotometric reagents since 1953 are reviewed.
H Chunlei et al.
Pharmacology & toxicology, 77(6), 386-390 (1995-12-01)
The effect of salicylaldoxime, 2-(OH)C6H4CH = NOH, on the resting membrane potential and action potential characteristics was studied using isolated right ventricular strips from rat heart. Salicylaldoxime (1-3 mM) reversibly hyperpolarized the cells, increased action potential amplitude, decreased the maximal...
Simone Bertini et al.
European journal of medicinal chemistry, 46(6), 2453-2462 (2011-04-13)
In a continuing effort to improve the subtype selectivity and agonist potency of estrogen receptor β (ERβ) ligands, we have designed and developed a thus far unexplored structural series obtained by molecular refinements of monoaryl-substituted salicylaldoximes (Salaldox B). The most...
F Minutolo et al.
Journal of medicinal chemistry, 44(24), 4288-4291 (2001-11-16)
The phenolic "A-ring" of natural and synthetic estrogen receptor (ER) ligands was effectively replaced by a planar six-member ring formed through an intramolecular hydrogen bond within a salicylaldoxime. Thus, oxime 1, a structural analogue of a triarylethylene estrogen, showed a...
Ting-Ting Zhao et al.
Bioorganic & medicinal chemistry, 20(10), 3233-3241 (2012-04-20)
A series of 2,6-dinitro-4-(trifluoromethyl)phenoxysalicylaldoxime derivatives (1h-20h) have been designed and synthesized, and their biological activities were also evaluated as potential antiproliferation and tubulin polymerization inhibitors. Among all the compounds, 2h showed the most potent activity in vitro, which inhibited the...
Ian A Gass et al.
Dalton transactions (Cambridge, England : 2003), (15)(15), 2043-2053 (2008-04-03)
The synthesis and magnetic properties of the compounds [HNEt(3)][Fe(2)(OMe)(Ph-sao)(2) (Ph-saoH)(2)].5MeOH (1.5MeOH), [Fe(3)O(Et-sao)(O(2)CPh)(5)(MeOH)(2)].3MeOH (2.3MeOH), [Fe(4)(Me-sao)(4)(Me-saoH)(4)] (3), [HNEt(3)](2)[Fe(6)O(2)(Me-sao)(4)(SO(4))(2)(OMe)(4)(MeOH)(2)] (4), [Fe(8)O(3)(Me-sao)(3)(tea)(teaH)(3)(O(2)CMe)(3)] (5), [Fe(8)O(3)(Et-sao)(3)(tea)(teaH)(3)(O(2)CMe)(3)] (6), and [Fe(8)O(3)(Ph-sao)(3)(tea)(teaH)(3)(O(2)CMe)(3)] (7) are reported (Me-saoH(2) is 2'-hydroxyacetophenone oxime, Et-saoH(2) is 2'-hydroxypropiophenone oxime and Ph-saoH(2) is 2-hydroxybenzophenone oxime). 1-7...
Ross S Forgan et al.
Chemical communications (Cambridge, England), (34)(34), 4049-4051 (2008-09-02)
Attaching dialkylaminomethyl arms to commercial phenolic oxime copper extractants yields reagents which transport base metal salts very efficiently by forming neutral 1:1 or 1:2 complexes with zwitterionic forms of the ligands.
Marco Wenzel et al.
Chemical communications (Cambridge, England), 47(1), 499-501 (2010-10-23)
The preferential uptake of sulfate over the industrially important anions, chloride and nitrate and structurally similar dihydrogen phosphate has been achieved in aqueous media with a dicopper salicylaldoxime complex.
Ross S Forgan et al.
Dalton transactions (Cambridge, England : 2003), 39(7), 1763-1770 (2010-05-08)
3-Dialkylaminomethyl substituted salicylaldoximes are efficient metal salt extractants, and, in contrast to related "salen"-based reagents, are sufficiently stable to acid hydrolysis to allow commercial application in base metal recovery. Crystal structures show that metal salts are bound by a zwitterionic...
Kyoko Yarimizu et al.
Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine, 32(1), 139-154 (2019-01-10)
Phytoplankton blooms can cause acute effects on marine ecosystems due either to their production of endogenous toxins or to their enormous biomass leading to major impacts on local economies and public health. Despite years of effort, the causes of these...
Min Li Yang et al.
Journal of molecular recognition : JMR, 18(1), 103-108 (2004-09-24)
In the report molecularly imprinted polymer (MIP) with salicylaldehyde-Cu(OAc)(2) as the template was synthesized and characterized by SEM, porosity and elemental analysis. Copper acetate was introduced since salicylaldehyde alone cannot display imprinting effect for its intramolecular hydrogen bond. The strong...
Irene A Zagol-Ikapitte et al.
Pharmaceutics, 2(1), 18-29 (2010-03-01)
Levels of reactive γ-ketoaldehydes derived from arachidonate increase in diseases associated with inflammation and oxidative injury. To assess the biological importance of these γ-ketoaldehydes, we previously identified salicylamine as an effective γ-ketoaldehyde scavenger in vitro and in cells. To determine...
Anna Tobiasz et al.
Talanta, 96, 82-88 (2012-07-24)
The paper presents application of a new resin dedicated to copper(II) flow-injection on-line preconcentration prior its flame atomic absorption spectrometric (FAAS) determination. The new sorbent, obtained by suspension polymerization technique, was styrene-divinylbenzene copolymer modified with 5-dodecylsalicylaldoxime-copper(II) complex. In flow mode...
Joel Tshuma et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 66(4-5), 879-883 (2006-08-01)
The equilibrium constants of salicylaldoxime in water at 25 degrees C, 0.5 M of ionic strength with NaCl and concentration of 1x10(-4) M were determined spectrophotometrically. The spectral data were processed using SQUAD program. The salicylaldoxime in acid medium has...
P W Crawford et al.
Free radical research communications, 3(6), 347-356 (1987-01-01)
The proposal is advanced that many anticancer agents may function via redox reactions resulting in generation of toxic oxy radicals which destroy neoplastic cells. Cyclic voltammetry was performed with some of the main types: iminium ions (protonated mAMSA derivatives), quinone...
Jiayi Wang et al.
Food chemistry, 245, 337-345 (2017-12-31)
A new micro-plate colorimetric assay was developed for rapid determination of zinc in animal feed, pet food and drinking water. Zinc ion was extracted from sample by trichloroacetic acid and then reacted with 2-(5-Bromo-2-pyridylazo)-5-[N-propyl-N-(3-sulfopropyl)amino]phenol (5-Br-PAPS) to form a Zn-PAPS complex...
Chrysa Kozoni et al.
Dalton transactions (Cambridge, England : 2003), 39(34), 7943-7950 (2010-08-04)
The reaction of MnCl(2).4H(2)O with DL-valine (Val) in MeOH in the presence of Et-saoH(2) (2-hydroxypropiophenone oxime) and NEt(4)OH forms the complex [Mn(III)(3)Mn(IV)(2)O(2)(CH(3)O)(Et-sao)(6)(Val)].Val.1.5H(2)O (1.Val.1.5H(2)O) in very good yields. A similar reaction of MnCl(2).4H(2)O with Glycine (Gly) in MeOH in the presence...
Dong-Mei Wu et al.
PloS one, 14(6), e0217431-e0217431 (2019-06-07)
Bacterioplankton play a key role in the global cycling of elements. To characterize the effects of hypoxia on bacterioplankton, bacterial community structure and function were investigated in the Changjiang Estuary. Water samples were collected from three layers (surface, middle, and...
Peter A Wood et al.
Acta crystallographica. Section B, Structural science, 62(Pt 6), 1099-1111 (2006-11-17)
The effect of pressure on the crystal structure of salicylaldoxime has been investigated. The ambient-pressure phase (salicylaldoxime-I) consists of pairs of molecules interacting through oximic OH...O hydrogen bonds; taken with phenolic OH...N intramolecular hydrogen bonds, these dimers form a pseudo-macrocycle...
Tiziano Tuccinardi et al.
Bioorganic & medicinal chemistry, 21(6), 1511-1515 (2012-09-29)
New compounds containing a novel zinc binding group (salicylaldoxime system) were identified as effective inhibitors of carbonic anhydrases (CAs). This structural motif seems to bind the catalytic zinc ion of CAs, revealing itself as a new valid alternative to the...
Laura Adamovicz et al.
Journal of experimental zoology. Part A, Ecological and integrative physiology, 333(10), 720-731 (2020-10-20)
Eastern (Terrapene carolina carolina) and ornate (Terrapene ornata ornata) box turtles have robust plasma antibacterial activity, however, the mechanism behind this activity is unknown. We used sheep red blood cell (SRBC) hemolysis assays, mannan-affinity chromatography, sodium dodecyl sulfate polyacrylamide gel...
Constantinos J Milios et al.
Dalton transactions (Cambridge, England : 2003), (14)(14), 1809-1817 (2008-03-29)
The use of derivatised salicylaldoximes in Mn chemistry has led to the isolation of a plethora of beautiful new SMMs ranging in nuclearity from three to eight and with spin ground states as large as S = 12-including a Mn6...
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