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Xian Fu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(38), 13357-13363 (2015-07-28)
A novel metal-doping strategy was developed for the construction of iron-decorated microporous aromatic polymers with high small-gas-uptake capacities. Cost-effective ferrocene-functionalized microporous aromatic polymers (FMAPs) were constructed by a one-step Friedel-Crafts reaction of ferrocene and s-triazine monomers. The introduction of ferrocene
Ravi Bhushan et al.
Journal of chromatography. A, 1217(41), 6382-6387 (2010-09-08)
Four dichloro-s-triazine (DCT) and five monochloro-s-triazine (MCT) chiral derivatizing reagents (CDRs) were synthesized by incorporating amino acid amide moieties as chiral auxiliaries in trichloro-s-triazine and its 6-methoxy derivative, respectively. Another MCT reagent was synthesized by substitution of two chlorine atoms
J. Mol. Catal., 80, 269-269 (1993)
Chao Gao et al.
Chemical communications (Cambridge, England), 49(11), 1127-1129 (2013-01-04)
A series of novel triazinonide-bridged bisimidazolium pincers were easily synthesized by quaternization of functionalized N-phenylimidazoles with highly reactive cyanuric chloride under mild conditions. The pincer was proven to be a very efficient ligand for in situ Pd-catalyzed Suzuki-Miyaura reaction with
Synthesis of acyl azides from carboxylic acids using cyanuric chloride
Bandgar BP and Pandit SS
Tetrahedron Letters, 43(18), 3413-3414 (2002)
Yu-Mee Wee et al.
Cell transplantation, 17(10-11), 1257-1269 (2009-02-03)
The necessity to transplant islet tissue without the need for immunosuppressant therapy has led to the development of materials for immune modulation. Pegylation makes islets antigenically silent, protecting them from the adsorption of foreign protein and thus avoiding immune injury.
Xue Jiang et al.
Bioresource technology, 104, 473-479 (2011-11-25)
The influence of introduction of cyanuric chloride on glucose's yield (Y) in acid-catalyzed hydrolysis of microcrystalline cellulose (MCC) has been studied. The content of cyanuric chloride (C) in modified MCCs was determined by X-ray photoelectric spectroscopy. The chemical structures of
A mild and efficient alternative to the classical Swern oxidation.
L De Luca et al.
The Journal of organic chemistry, 66(23), 7907-7909 (2001-11-10)
Ravi Bhushan et al.
Amino acids, 42(4), 1371-1378 (2011-01-20)
Six dichloro-s-triazine (DCT) reagents having L-Leu, D-Phg, L-Val, L-Met, L-Ala and L-Met-NH(2) as chiral auxiliaries in cyanuric chloride were introduced for enantioseparation of 13 proteinogenic amino acids. Four other DCTs and six monochloro-s-triazine (MCT) reagents having amino acid amides as
Wenjin Wang et al.
Talanta, 190, 327-334 (2018-09-03)
A novel nanoporous carbon (NPC) was constructed by utilizing the porous aromatic framework-6 (PAF-6) as both the template and carbon source along with KOH as a chemical activator. The newly-synthesized PAF-6 derived nanoporous carbon (PAF-6-NPC) was then employed as a
Ramin Ghorbani-Vaghei et al.
Molecular diversity, 14(2), 385-392 (2009-08-08)
A new, facile, and efficient procedure for conjugate addition of indole and pyrrole with Michael acceptors have been developed for pulverization-activation reaction catalyzed by wet cyanuric chloride (2,4,6-trichloro-[1,3,5]-triazine or TCT) through grinding under solvent-free conditions at room temperature. Also, double-conjugate
Der-Yen Lee et al.
Journal of chromatography. A, 1388, 60-68 (2015-03-04)
Electrospray ionization (ESI) is the most useful interface for mass spectrometry associated with liquid chromatography (LC). However, analyses of polar metabolites become a challenge because the high polarity impairs the separation of metabolites in reversed-phase liquid chromatography and ionization of
Peter H Huy et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 24(29), 7410-7416 (2018-03-07)
A general formamide-catalyzed protocol for the efficient transformation of alcohols into alkyl chlorides, which is promoted by substoichiometric amounts (down to 34 mol %) of inexpensive trichlorotriazine (TCT), is introduced. This is the first example of a TCT-mediated dihydroxychlorination of an OH-containing
Yoshiro Furuya et al.
Journal of the American Chemical Society, 127(32), 11240-11241 (2005-08-11)
The first general organocatalytic Beckmann rearrangement of ketoximes into amides has been realized by the catalytic use of cyanuric chloride. Furthermore, acids such as HCl and ZnCl2 are effective as cocatalysts with cyanuric chloride. For example, azacyclotridecan-2-one, which is synthetically
Johan Alftrén et al.
Applied biochemistry and biotechnology, 169(7), 2076-2087 (2013-02-02)
β-Glucosidase hydrolyzes cellobiose to glucose and is an important enzyme in the consortium used for hydrolysis of cellulosic and lignocellulosic feedstocks. In the present work, β-glucosidase was covalently immobilized on non-porous magnetic particles to enable re-use of the enzyme. It
Sanjay K Singh et al.
Frontiers in immunology, 11, 1812-1812 (2020-09-10)
C-reactive protein (CRP), a component of the innate immune system, is an antipneumococcal plasma protein. Human CRP has been shown to protect mice against infection with lethal doses of Streptococcus pneumoniae by decreasing bacteremia. in vitro, CRP binds to phosphocholine-containing
Yue Wang et al.
Analytical and bioanalytical chemistry, 399(3), 1151-1162 (2010-11-03)
Tyrosinase (TYR: EC was covalently modified onto the surface of a cyanuric chloride-activated carbon felt (CF) from the mixed buffer solution of TYR and acridine orange (AO). The resulting TYR-immobilized CF (TYR/AO-CF) was used as a working electrode unit
A Atef El-Sayed et al.
International journal of biological macromolecules, 50(1), 273-276 (2011-11-26)
In the present study salicylanilide was reacted with 2,4,6-trichloro-1,3,5-triazine producing reactive salicylanilide at a yield of 45% according to reaction conditions set. The reactive salicylanilide was confirmed structurally through FT-IR analysis. Pristine viscose fabric was treated with active salicylanilide to
R A Lazar et al.
Journal of chromatography. A, 1394, 148-153 (2015-04-05)
Micro-capillary film (MCF) membranes are effective platforms for bioseparations and viable alternatives to established packed bed and membrane substrates at the analytical and preparative chromatography scales. Single hollow fibre (HF) MCF membranes with varied microstructures were produced in order to
Moni Sharma et al.
The Journal of organic chemistry, 77(2), 929-937 (2011-12-21)
We have developed an efficient cyanuric chloride (2,4,6-trichloro-1,3,5-triazine, TCT) catalyzed approach for the synthesis of 2,3-dihydroquinazolin-4(1H)-one (3a-3x), 2-spiroquinazolinone (5, 7), and glycoconjugates of 2,3-dihydroquinazolin-4(1H)-one (10a, 10b) derivatives. The reaction allows rapid cyclization (8-20 min) with 10 mol % cyanuric chloride
Kaiqiang Zhang et al.
Carbohydrate polymers, 196, 209-216 (2018-06-13)
A thermo and pH dual-responsive starch (TPDS) was successfully synthesized by etherification, in which butyl glycidyl ether (BGE) was used as the hydrophobic reagent followed by addition of 2-chloro-4, 6-diglycino-[1,3,5]-triazine (CDT) groups. The obtained materials were characterized by Fourier transform-infrared
Morten Hansen et al.
Journal of biomedical materials research. Part A, 96(2), 372-383 (2010-12-21)
Standard cell culture plastic was surface modified by passive adsorption or covalent attachment of interleukin (IL)-4 and investigated for its ability to induce differentiation of human monocytes into mature dendritic cells, a process dose-dependently regulated by IL-4. Covalent attachment of
Ravi Bhushan et al.
Amino acids, 42(4), 1417-1423 (2011-02-05)
L-Ala-NH(2), L-Val-NH(2), L-Leu-NH(2), and D-Phg-NH(2) were used as chiral auxiliaries to synthesize four chiral derivatizing reagents (CDRs) of each of the three categories, viz., difluoro dinitro benzene (DFDNB) based chiral variants, and cyanuric chloride (CC) based monochloro-s-triazine reagents (MCTs) and
Lijuan Song et al.
Analytica chimica acta, 703(2), 257-263 (2011-09-06)
A fast, simple and cost-effective one-pot labeling strategy coupled with capillary zone electrophoresis was developed for the complete separation of amino acid mixture. The strategy includes two steps of reactions: Cyanuric chloride was made to react first with 7-amino-1,3-naphthalenedisulfonic acid
Mehdi Shariat et al.
Molecules (Basel, Switzerland), 17(10), 11607-11615 (2012-10-02)
A new and efficient method has been designed to prepare 2,2'-arylene-substituted bis(4H-3,1-benzoxazin-4-one) derivatives by using the mixture of cyanuric chloride and N,N-dimethylformamide in a microwave-assisted reaction. The method used and presented here has good rate enhancement and excellent yields.
Enantiomeric purity of chiral derivatizing reagents for enantioresolution.
Ravi Bhushan
Bioanalysis, 3(18), 2057-2060 (2011-09-29)
Neema Kassim et al.
Journal of microbiology and biotechnology, 23(4), 527-533 (2013-04-10)
Polyclonal antibodies labeled with a tracer have been commonly used as secondary antibodies in immunochemical assays to quantify the concentration of antibody-antigen complexes. The majority of these antibodies conjugated with a tracer are commercially available, with the exception of few
Kun Zhang et al.
Analytica chimica acta, 1144, 34-42 (2021-01-18)
Herein, we report our strategy to develop the efficient chemosensor and real-time monitoring technique for cyanuric chloride (TCT) detection. A luminescent macrocyclic mononuclear Sm(III) complex Sm-2k bearing with two dynamic imine bonds has been constructed via the template synthesis between
Ravi Bhushan et al.
Journal of chromatography. A, 1217(49), 7669-7676 (2010-11-03)
A new series of chiral derivatizing reagents (CDRs) consisting of four dichloro-s-triazine reagents was synthesized by nucleophilic substitution of one chlorine atom in trichloro-s-triazine with amino acids, namely L-Leu, D-Phg, L-Val and L-Ala as chiral auxiliaries. Two other sets of
Eric Loeser
Journal of chromatography. A, 1218(22), 3565-3570 (2011-05-03)
Diastereomeric derivatives prepared from an amino acid and an amino amide using trichloro s-triazine as a coupling platform are known to produce good chromatographic diastereoselectivity for many amino acid analytes. The chromatographic diastereoselectivity of these derivatives is difficult to rationalize
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