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Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides.

Organic & biomolecular chemistry (2011-03-08)
Christian Bukovec, Uli Kazmaier
ABSTRACT

Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized building blocks in excellent yields.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Sodium amide, 95%
Sigma-Aldrich
Sodium amide, 98%
Sigma-Aldrich
Sodium amide, 50 wt. % suspension in toluene

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