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[Preparation of gas chromatographic capillary columns with beta-cyclodextrin polymer stationary phase modified with methyl phenyl silicone(OV-17)].

Se pu = Chinese journal of chromatography (2003-01-25)
G B Chen, K W Tang
ABSTRACT

An insoluble beta-cyclodextrin polymer cross-linked with epichlorohydrin was prepared. beta-Cyclodextrin polymer (0.26 g) was treated for 0.5 h by a ultrasonator in the mixed solvent (10 mL) of isopropyl ether, methylene dichloride and benzene with a volume ratio 2:1:2, and a 26 g/L colloidal stationary liquid was prepared. It was coated on a fused silica capillary by superdynamic coating method. The capillary column was of high column efficiency of above 3,000/m with good thermal stability and moderate polarity. Enantiomers of xylene, dichlorobenzene, alpha-pinene, beta-pinene, ethyl lactate, alpha-phenyl ethanol, 1, 2-propanediol, alpha-lonone, methyl alpha-chloropropionate and gamma-valerolactone were separated on the capillary column. The experimental results showed that beta-cyclodextrin polymer treated by a ultrasonator is a capillary chromatographic stationary phase with good performance and high selectivity.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Silicone oil AR 20, viscosity ~20 mPa.s,   neat(25 °C)
Sigma-Aldrich
Silicone oil AP 100, viscosity ~100 mPa.s,   neat(25 °C)
Sigma-Aldrich
Poly(methylphenylsiloxane), viscosity 450-550 cSt 
Sigma-Aldrich
Silicone oil AR 200, viscosity ~200 mPa.s,   neat(25 °C)
Sigma-Aldrich
Silicone oil AP 1000, viscosity ~1000 mPa.s,   neat(25 °C)

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