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  • Addition to electron deficient olefins of alpha-oxy carbon- centered radicals, generated from cyclic ethers and acetals by the reaction with alkylperoxy- lambda(3)-iodane.

Addition to electron deficient olefins of alpha-oxy carbon- centered radicals, generated from cyclic ethers and acetals by the reaction with alkylperoxy- lambda(3)-iodane.

Molecules (Basel, Switzerland) (2007-11-17)
Takuya Sueda, Yasunori Takeuchi, Takashi Suefuji, Masahito Ochiai
ABSTRACT

Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 degrees C generates alpha-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Phenyl vinyl sulfone, 99%