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[Oxidation of dermatan sulfate with a NaOCl-NaBr-2,2,6,6-tetramethylpiperidine-1-oxyl reagent in the water medium].

Bioorganicheskaia khimiia (2010-07-21)
I Iu Ponedel'kina, E A Khaĭbrakhmanova, V N Odinokov, L M Khalilov, U M Dzhemilev
ABSTRACT

The oxidation of primary hydroxyl groups in dermatan sulfate with the NaOCl-NaBr-2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) reagent in an aqueous alkaline environment was carried out for the first time. Modified dermatan sulfates containing hydrated aldehyde (15-50%) and carboxyl (25-100%) groups were obtained.

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