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Indium(III) halide-catalyzed UV-irradiated radical coupling of iodomethylphosphorus compounds with various organostannanes.

Organic letters (2013-03-23)
Itaru Suzuki, Kensuke Kiyokawa, Makoto Yasuda, Akio Baba
ABSTRACT

The first catalytic radical coupling of iodomethylphosphorus compounds was accomplished with allyl-, alkenyl-, and allenylstannanes under UV irradiation in the presence of an indium(III) halide catalyst, for which a transmetalated allylic indium species was confirmed to be an active radical species.

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