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Carbon-sulfur bond formation catalyzed by [Pd(IPr*(OMe))(cin)Cl] (cin = cinnamyl).

The Journal of organic chemistry (2013-08-14)
Gulluzar Bastug, Steven P Nolan
ABSTRACT

The newly prepared complex [Pd(IPr*(OMe))(cin)(Cl)] provides high catalytic activity for carbon-sulfur cross-coupling reactions. Nonactivated and deactivated aryl halides were successfully coupled with a large variety of aryl- and alkylthiols using this well-defined palladium N-heterocyclic carbene (NHC) complex.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Sulfur, 99.998% trace metals basis
Sigma-Aldrich
Sulfur, powder, 99.98% trace metals basis
Supelco
Sulfur, PESTANAL®, analytical standard
Sigma-Aldrich
Sulfur, flakes, ≥99.99% trace metals basis