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Diastereoselective formal synthesis of a monoterpene alkaloid, (-)-incarvilline.

The Journal of organic chemistry (2007-07-31)
Toshio Honda, Kyosuke Kaneda
ABSTRACT

Diastereoselective formal synthesis of a monoterpene alkaloid, (-)-incarvilline, the key intermediate for the synthesis of (-)-incarvillateine, was achieved by using an intramolecular Pauson-Khand reaction of (S)-N-[(E)-2-butenyl]-N-(3-butynyl-2-methoxymethoxy)-p-toluenesulfonamide as a key step.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
N-(tert-Butoxycarbonyl)-p-toluenesulfonamide

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