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Interface Promoted Reversible Mg Insertion in Nanostructured Tin-Antimony Alloys.

Advanced materials (Deerfield Beach, Fla.) (2015-10-01)
Yingwen Cheng, Yuyan Shao, Lucas R Parent, Maria L Sushko, Guosheng Li, Peter V Sushko, Nigel D Browning, Chongmin Wang, Jun Liu
ABSTRACT

An interface promoted approach is developed for guiding the design of stable and high capacity materials for Mg batteries using SnSb alloys as model materials. Experimental and theoretical studies reveal that the SnSb alloy has exceptionally high reversible capacity (420 mA h g(-1)), excellent rate capability, and good cyclic stability for hosting Mg ions due to the stabilization/promotion effects of the interfaces between the multicomponent phases generated during repeated magnesiation-demagnesiation.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
BES, ≥99.0% (titration)
Sigma-Aldrich
BES, BioPerformance Certified, suitable for cell culture, ≥99.0%
Sigma-Aldrich
BES, BioXtra, ≥99.0% (titration)
Sigma-Aldrich
BES, BioXtra, for molecular biology, ≥99.5% (T)

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