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Alkylation of active methylene compounds with alcohols catalyzed by an iridium complex.

Chemical communications (Cambridge, England) (2007-07-05)
Masao Morita, Yasushi Obora, Yasutaka Ishii
ABSTRACT

Base-free catalytic alpha-alkylation of active methylene compounds with primary alcohols was successfully achieved using an [IrCl(cod)](2) complex in the presence of PPh(3) to afford the corresponding saturated alpha-alkylated products in good yields.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
2-(Benzyloxy)ethanol, 98%

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