Bright triplet excitons in caesium lead halide perovskites.

Nature (2018-01-13)
Michael A Becker, Roman Vaxenburg, Georgian Nedelcu, Peter C Sercel, Andrew Shabaev, Michael J Mehl, John G Michopoulos, Samuel G Lambrakos, Noam Bernstein, John L Lyons, Thilo Stöferle, Rainer F Mahrt, Maksym V Kovalenko, David J Norris, Gabriele Rainò, Alexander L Efros
ABSTRACT

Nanostructured semiconductors emit light from electronic states known as excitons. For organic materials, Hund's rules state that the lowest-energy exciton is a poorly emitting triplet state. For inorganic semiconductors, similar rules predict an analogue of this triplet state known as the 'dark exciton'. Because dark excitons release photons slowly, hindering emission from inorganic nanostructures, materials that disobey these rules have been sought. However, despite considerable experimental and theoretical efforts, no inorganic semiconductors have been identified in which the lowest exciton is bright. Here we show that the lowest exciton in caesium lead halide perovskites (CsPbX

MATERIALS
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Sigma-Aldrich
Cesium carbonate, 99.9% trace metals basis

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