Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
310468
Cloruro de litio
ACS reagent, ≥99%
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$244.00
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About This Item
$244.00
En stockDetalles
Productos recomendados
grado
ACS reagent
Nivel de calidad
Ensayo
≥99%
Formulario
crystalline powder
powder, crystals or granules
impurezas
≤0.008 meq/g Titr. base
≤0.01% insolubles
pérdida
≤1.0% loss on drying
pH
6
mp
605 °C (lit.)
trazas de anión
sulfate (SO42-): ≤0.01%
trazas de catión
Ba: ≤0.003%
Ca: ≤0.01%
Fe: ≤0.001%
K: ≤0.01%
Na: ≤0.20%
heavy metals: ≤0.002% (by ICP)
cadena SMILES
[Li+].[Cl-]
InChI
1S/ClH.Li/h1H;/q;+1/p-1
Clave InChI
KWGKDLIKAYFUFQ-UHFFFAOYSA-M
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Este artículo | 746460 | 203637 | 73036 |
---|---|---|---|
form crystalline powder, powder, crystals or granules | form powder | form powder | form powder or crystals |
assay ≥99% | assay ≥99% | assay ≥99.98% trace metals basis | assay ≥99.0% (AT) |
Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 200 |
grade ACS reagent | grade ACS reagent, anhydrous | grade - | grade - |
impurities ≤0.008 meq/g Titr. base, ≤0.01% insolubles | impurities ≤0.008 meq/g Titr. base, ≤0.01% insolubles | impurities ≤100.0 ppm Trace Metal Analysis | impurities - |
mp 605 °C (lit.) | mp 605 °C (lit.) | mp 605 °C (lit.) | mp 605 °C (lit.) |
Descripción general
Aplicación
- A source of chloride anion for the conversion of alcohols to alkyl chloride under Mitsunobu conditions.
- An additive in the palladium-catalyzed coupling and carbonylative coupling reactions of organostannanes and vinyl triflates.
- A reagent for the cleavage of protecting groups under mild conditions. It readily converts acetals and ketals to the corresponding carbonyl compounds.
- A reagent in the dehydrohalogenation of α-halocarbonyl compounds to α,β-unsaturated carbonyls compound in the presence of DMF.
LiCl is also used with other reagents:
- LiCl:DIPEA (1:1 molar ratio) is used in Horner–Wadsworth–Emmons alkenation reaction.
- LiCl:Hexamethylphosphoric triamide is used in decarboxylative alkylation and chloride displacement reactions.
- LiCl is used as an additive in solid-phase peptide synthesis because it increases resin swelling and improves the efficiencies of complex coupling steps.
Características y beneficios
- Easy to handle
- Weak Lewis acid
- Highly soluble in water
Otras notas
Información legal
Palabra de señalización
Warning
Frases de peligro
Consejos de prudencia
Clasificaciones de peligro
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2
Código de clase de almacenamiento
13 - Non Combustible Solids
Clase de riesgo para el agua (WGK)
WGK 1
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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