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Merck

72253

Nickel(II) nitrate hexahydrate

purum p.a., crystallized, ≥97.0% (KT)

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About This Item

Công thức tuyến tính:
Ni(NO3)2 · 6H2O
CAS Number:
Trọng lượng phân tử:
290.79
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.21
Assay:
≥97.0% (KT)
Form:
crystals

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grade

purum p.a.

Quality Level

assay

≥97.0% (KT)

form

crystals

quality

crystallized

mp

56 °C (lit.)

density

2.05 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤500 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Na: ≤100 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES string

O.O.O.O.O.O.[Ni++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/2NO3.Ni.6H2O/c2*2-1(3)4;;;;;;;/h;;;6*1H2/q2*-1;+2;;;;;;

InChI key

AOPCKOPZYFFEDA-UHFFFAOYSA-N

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Hiển thị điểm khác biệt

1 of 4

Mặt hàng này
722521.06721244074
form

crystals

form

crystals or chunks

form

solid

form

crystals

assay

≥97.0% (KT)

assay

≥98.5% (KT)

assay

99.0-102.0% (complexometric)

assay

94.5-105.5% (EDTA titration)

Quality Level

200

Quality Level

200

Quality Level

300

Quality Level

100

grade

purum p.a.

grade

puriss. p.a.

grade

-

grade

-

cation traces

Ca: ≤50 mg/kg, Co: ≤500 mg/kg, Fe: ≤50 mg/kg, Na: ≤100 mg/kg, Zn: ≤50 mg/kg, Cd: ≤50 mg/kg, K: ≤100 mg/kg, Cu: ≤50 mg/kg, Pb: ≤50 mg/kg

cation traces

Ca: ≤10 mg/kg, Cd: ≤10 mg/kg, Co: ≤100 mg/kg, Cu: ≤20 mg/kg, Fe: ≤10 mg/kg, K: ≤50 mg/kg, Na: ≤50 mg/kg, Pb: ≤10 mg/kg, Zn: ≤10 mg/kg

cation traces

Ca: ≤0.005%, Co: ≤0.005%, Cu: ≤0.0005%, Fe: ≤0.001%, K: ≤0.01%, Mg: ≤0.01%, Mn: ≤0.002%, NH4+: ≤0.05%, Na: ≤0.005%, Pb: ≤0.001%, Zn: ≤0.001%

cation traces

-

mp

56 °C (lit.)

mp

56 °C (lit.)

mp

56.7 °C

mp

56 °C (lit.)

General description

Nickel(II) nitrate hexahydrate (Ni(NO3)2.6H2O) is a hydrated nickel(II) salt. Its thermal degradation has been investigated by thermogravimetric methods under quasi-isothermal conditions.[1]

Application

Nickel(II) nitrate hexahydrate may be used as precursor for the synthesis of [Ni1/3Co1/3Mn1/3]O2 powders[2] and Ni (II) oxide aerogels.[3]

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Lớp lưu trữ

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Chọn một trong những phiên bản gần đây nhất:

Giấy chứng nhận phân tích (COA)

Lot/Batch Number

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Truy cập thư viện tài liệu

Monolithic nickel (II)-based aerogels using an organic epoxide: the importance of the counterion.
Gash AE, et al.
Journal of Non-Crystalline Solids, 350, 145-151 (2004)
Thermal decomposition of nickel nitrate hexahydrate, Ni(NO3)2?6H2O, in comparison to Co(NO3)2?6H2O and Ca(NO3)2?4H2O.
Brockner W, et al.
Thermochimica Acta, 456(1), 64-68 (2007)
Synthesis and structural characterization of layered Li[Ni1/3Co1/3Mn1/3]O2 cathode materials by ultrasonic spray pyrolysis method.
Park SH, et al.
Electrochimica Acta, 49(4), 557-563 (2004)
Marisa Freitas et al.
Biometals : an international journal on the role of metal ions in biology, biochemistry, and medicine, 26(1), 13-21 (2012-10-26)
Nickel is an ubiquitous transition metal that is industrially applied in many forms, which inevitably leads to a high degree of occupational and environmental exposure. Over-exposure to nickel can produce a variety of adverse effects on human health, including allergy
Nickel nitrate and K-ferrocyanide in fixative for electron microscopy as tracer of extracellular space.
L S Gutiérrez et al.
Microscopia electronica y biologia celular : organo oficial de las Sociedades Latinoamericana de Microscopia Electronica e Iberoamericana de Biologia Celular, 12(2), 217-229 (1988-12-01)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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