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Organic letters

Concise total synthesis of (+/-)-aloperine and 6-epi-aloperine.


PMID 12182590

Abstract

[reaction: see text] Total synthesis of aloperine and 6-epi-aloperine is reported. The crucial steps of the synthetic strategy are an aza-annulation reaction and an intermolecular Diels-Alder reaction. The synthetic plan proceeds from commercially available piperidine-2-ethanol.

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546704
Aloperine, 96%
C15H24N2