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The Journal of organic chemistry

Reactions of methylenecyclopropanes with phenylsulfenyl chloride and phenylselenyl chloride.


PMID 15074931

Abstract

The reaction of methylenecyclopropanes 1 with phenylsulfenyl chloride or phenylselenyl chloride gives (cyclobut-1-enylsulfanyl)benzene or (cyclobut-1-enylselanyl)benzene along with ring-opened product in good total yields at 0 degrees C in various solvents. A plausible mechanism has been proposed.

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183342
Phenylselenyl chloride, 98%
C6H5ClSe