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Journal of the American Chemical Society

Transnitrosation of nitrosothiols: characterization of an elusive intermediate.


PMID 15643848

Abstract

We report an investigation of the reaction between (S)-nitroso-l-cysteine ethyl ester and l-cysteine ethyl ester as a model of physiologically relevant transnitrosation processes. Our theoretical and experimental evidence clearly supports the existence of a nitroxyl disulfide intermediate in solution.

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