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Rapid communications in mass spectrometry : RCM

The inactivation of phospholipase A2 by scalaradial: a biomimetic study by electrospray mass spectrometry.


PMID 15645482

Abstract

A biomimetic approach was employed to shed light on the nature of chemical reactions occurring in the covalent inactivation of phospholipase A(2) (PLA(2)) by scalaradial (1), a marine dialdehyde terpenoid endowed with potent anti-inflammatory activity. To this end, a detailed study of the reaction profile between the nitrogenous nucleophile isopropylamine and scalaradial was performed under biologically relevant conditions.

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