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Guang pu xue yu guang pu fen xi = Guang pu

[Study on the synergistic coloration of tin (II) with pyrocatechol violet and rhodamine B and its application].


PMID 15822291

Abstract

In the presence of PVA, a sensitive color reaction of tin (I ) on pyrocatechol violet and rhodamine B has been studied. In a NaAc-HAc (pH = 5.0) medium, tin(II) ions form an ions-associate complex with pyrocatechol violet and rhodamine B. The composition of the complex is Sn (II): PV : RhB = 1 : 2: 4. The maximum absorption of the ions-associate complex is at 560 nm with an apparent molar absorptivity of 1.18 x 10(5) L x mol(-1) x cm(-1). Beer's law is obeyed in the range of 0-15 microg/25 mL of tin. The method is highly selective and has been applied to the determination of trace tin in some objects with satisfactory results.

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Pyrocatechol Violet, suitable for indicator
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