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Organic & biomolecular chemistry

Selective synthesis of C-arylglycosides via Cp*RuCl-catalyzed partially intramolecular cyclotrimerizations of C-alkynylglycosides.


PMID 15858662

Abstract

In the presence of catalytic amounts of Cp*RuCl(cod), the partially intramolecular cyclotrimerizations of various C-alkynylglycosides and C-diynylglycosides proceeded at ambient temperature to afford C-arylglycosides.

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208523
Ruthenium(III) chloride, Ru content 45-55%
Cl3Ru