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Shokuhin eiseigaku zasshi. Journal of the Food Hygienic Society of Japan

[Analysis of disulfoton sulfoxide in chingentsuai by pulsed splitless mass spectrometry using programmed temperature vaporization (PTV) inlet].


PMID 16862987

Abstract

A peak considered to be due to disulfoton sulfoxide as a metabolite of disulfoton was detected in the analysis of the chingentsuai extraction solution of vegetables by GC-FPD. In the analysis by GC/MS for identification, though the retention time and the mass spectrum were the same as those of the standard, the spectrum was different from MS library data. It appeared that decomposition of disulfoton sulfoxide occurred at the inlet. Therefore, we used a programmed temperature vaporization (PTV) inlet in the pulsed splitless mode to achieve a low inlet temperature and high injection pressure. As a result, the expected mass spectrum of disulfoton sulfoxide was obtained. Under this condition, the peak obtained from chingentsuai was identified as disulfoton sulfoxide. Disulfoton sulfoxide was detected from 2 of 25 chingentsuai samples, at concentrations of 0.66 microg/g and 0.14 microg/g.

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Disulfoton, PESTANAL®, analytical standard
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