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Organic & biomolecular chemistry

The first catalytic Sakurai reaction of N-alkoxycarbonylamino sulfones with allyltrimethylsilane.


PMID 17268636

Abstract

We report the first catalytic Sakurai reaction of N-alkoxycarbonylamino sulfones with allylsilanes. The allylation reaction of N-alkoxycarbonylamino phenylsulfones with allyltrimethylsilane proceeded smoothly with low catalyst loading of bismuth triflate (2.0 mol%) to afford the corresponding protected homoallylic amines in moderate to very good yields (up to 96%).

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208264
Allyltrimethylsilane, 98%
C6H14Si