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The Journal of organic chemistry

Syntheses of novel chiral sulfinamido ligands and their applications in diethylzinc additions to aldehydes.


PMID 17288383

Abstract

A novel class of sulfinamido alcohol ligands 1-6 was synthesized from (S)-tert-butanesulfinamide. These ligands showed excellent catalytic activities and enantiomeric selectivities in asymmetric additions of diethylzinc to aromatic aldehydes.