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The Journal of organic chemistry

From furans to anilines: toward one-pot two-step amination/diels-alder sequences.


PMID 18302410

Abstract

Selective metal-free amination and Diels-Alder reactions are described in the furan series, leading to polysubstituted anilines or to stable oxabicyclic adducts in high yield. Interestingly, anilines are conveniently prepared through a novel one-pot, two-step amination/Diels-Alder procedure from commercially available 5-bromo-2-furaldehyde.

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433985
5-Bromo-2-furaldehyde, 97%
C5H3BrO2