EMAIL THIS PAGE TO A FRIEND

Journal of the American Chemical Society

Controlled cyclopolymerization through quantitative 19-membered ring formation.


PMID 18652466

Abstract

Cyclopolymerization of a bis-methacrylate monomer derived from trans-cyclohexanediol and 2-methacryloyloxyethyl isocyanate proceeded through 19-membered ring formation. The unusual large ring formation originated from the designed steric regulation by the cyclohexane ring and the hydrogen bonds. The RAFT polymerization employing cumyl dithiobenzoate attained controlled polymerization, which supported the quantitative cyclization.

Related Materials

Product #

Image

Description

Molecular Formula

Add to Cart

477060
2-Isocyanatoethyl methacrylate, contains ≤0.1% BHT as inhibitor, 98%
C7H9NO3