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The Journal of organic chemistry

De novo synthesis of (+)-isofregenedol.


PMID 18698826

Abstract

An efficient enantioselective synthesis of (+)-isofregenedol was achieved in 13 steps from commercially available cyclohexene oxide without the use of protecting groups. The tetrahydronaphthalenic core of isofregenedol was obtained via a gold(I)-catalyzed benzannulation recently developed in our laboratory.

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C102504
Cyclohexene oxide, 98%
C6H10O