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Chemical communications (Cambridge, England)

Concise total synthesis of (+/-)-aspidospermidine via an oxidative Hosomi-Sakurai process.


PMID 19436917

Abstract

A concise total synthesis of (+/-)-aspidospermidine has been achieved in twelve steps from inexpensive 4-ethylphenol, based on an oxidative Hosomi-Sakurai reaction via the concept of "aromatic ring umpolung".

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