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Chemical communications (Cambridge, England)

Evidence for the formation of a mononuclear ferric-hydroperoxo complex via the reaction of dioxygen with an (N4S(thiolate))iron(II) complex.


PMID 19885493

Abstract

Addition of O(2)(g) at low-temperature to a mononuclear, nonheme iron(ii) complex comprising a tetraazamacrocyclic N(4) donor and an arylthiolate S donor leads to the generation of a deep red complex assigned as a low-spin Fe(III)?OOH complex, formed via metal- and ligand-assisted oxidation.

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