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Inorganic chemistry

Titanocene difluorides with improved cytotoxic activity.


PMID 20055428

Abstract

Titanocene difluorides can be obtained by halide metathesis of the respective titanocene dichlorides with trimethyltin fluoride (Me(3)SnF), giving access to a new class of cytotoxic active substances. Furthermore, an improved method for the synthesis of diaryl-substituted titanocene dichlorides is presented.

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234826
Bis(cyclopentadienyl)titanium(IV) dichloride, 97%
C10H10Cl2Ti