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Organic & biomolecular chemistry

Nucleophilic heterocyclic carbene as a novel catalyst for cyclopropanation of cyano acrylates.


PMID 20135050

Abstract

Nucleophilic heterocyclic carbenes (NHCs) have been used for the first time as catalysts in the cyclopropanation of ethyl cyanocinnamates with phenacyl bromide by Michael-initiated ring-closure (MIRC).

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