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Preparative biochemistry & biotechnology

1,6-Hexanediamine methanesulfonate: a mild and efficient catalyst for the tetrahydropyranylation of alcohols under solvent-free conditions.


PMID 20623428

Abstract

Various alcohols react with 3,4-dihydro-2 H-pyran under mild conditions using a catalytic amount of 1,6-hexanediamine methanesulfonate. It affords the corresponding tetrahydropyranyl ethers in good yields at a faster rate in the absence of solvent.

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