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Journal of the American Chemical Society

Redox-neutral indole annulation cascades.


PMID 21280625

Abstract

Aminobenzaldehydes react with indoles in an unprecedented cascade reaction. This acid-catalyzed redox-neutral annulation proceeds via a condensation/1,5-hydride shift/ring-closure sequence. Polycyclic azepinoindoles and related compounds are obtained in a single step with good to excellent yields.

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A9628
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