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Journal of the American Chemical Society

Rhodium-catalyzed enantioselective addition of boronic acids to N-benzylnicotinate salts.


PMID 21309573

Abstract

The highly enantioselective catalytic asymmetric addition of aryl and alkenylboronic acids to N-benzylnicotinate salt 1 is described. The dihydropyridine 2 reaction products can be converted to synthetically useful piperidines. Application of the methodology to the preparation of enantioenriched quaternary chiral centers is also discussed.

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72351
Benzyl nicotinate, ≥98.0% (GC)
C13H11NO2