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Chemical communications (Cambridge, England)

The two spin states of an end-on copper(II)-superoxide mimic.


PMID 21681293

Abstract

The reaction of nitrosobenzene with copper(I) complexes of a tetradentate ligand led to two novel species that are best described as copper(II) complexes of an O-bonded nitrosobenzyl radical anion, in either the singlet or the triplet spin-state. Both states were characterized by crystal structures, magnetic measurements and DFT calculations.

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N24609
Nitrosobenzene, ≥97%
C6H5NO