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Organic letters

Expedient Route to the functionalized calyciphylline A-type skeleton via a Michael addition-RCM strategy.


PMID 21899283

Abstract

An efficient, robust, and scalable strategy to access the functionalized core of calyciphylline A-type alkaloids has been developed starting from commercially available 3-methylanisole. Key features of this approach are an intramolecular Michael addition/allylation sequence and a ring-closing metathesis step.

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149160
3-Methylanisole, 99%
C8H10O